Citation: Ding Qiao YANG, He Ping ZENG. Regio-and Diasteroselectivity of Rhodium-catalyzed Ring Opening Reaction of Oxabenzonorbornadienes with Heteroatom Nucleophiles[J]. Chinese Chemical Letters, ;2003, 14(7): 697-699. shu

Regio-and Diasteroselectivity of Rhodium-catalyzed Ring Opening Reaction of Oxabenzonorbornadienes with Heteroatom Nucleophiles

Department of Chemistry, South China Normal University, Guangzhou 510631

Received Date: 26 August 2002

A new rhodium catalyzed ring opening reaction of oxabenzonorbornadienes and its derivatives was described. This reaction forms a new carbon-nitrogen bond via an intermolecular allylic displacement of the bridgehead oxygen with a piperazine's derivatives, which proceeds with very high regioselectivity.
- Ring opening,
- rhodium-catalyzed,
- oxabenzonorbornadienes,
- heteroatom nucleophiles
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