Citation: Xiao-Jiang HAO, Manabu NODE, Kaoru FUJI. Chiral Synthesis of the Key Intermediate of Diterpenoids[J]. Chinese Chemical Letters, ;1997, 8(11): 949-950. shu

Chiral Synthesis of the Key Intermediate of Diterpenoids

a Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650204;
b Kyoto Pharmaceutical University, Yamashina-ku, Kyoto 607, Japan;
c Institute for Chemical Research, Kyoto University, Uji 611, Japan

Received Date: 4 September 1997

(-)-Methyl(4R,5S,10R)-14-methoxypodocarpa-8,11,13-triene-19-oate(1),which is the key intermediate for synthesis of diterpenoids,was synthesized from (R)-(+)-2-methyl-2-(2'-nitrovinyl)-δ-valerolactone (2).
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