Citation: Xiao Hua CHEN, Long Gen ZHU, N. M. Kostic. HYDROLYTIC CLEAVAGE OF ACMET-GLY PROMOTED BY CIS-[Pd(MET)(D₂O)₂](NO₃)₂[J]. Chinese Chemical Letters, ;1996, 7(2): 127-128. shu

HYDROLYTIC CLEAVAGE OF ACMET-GLY PROMOTED BY CIS-[Pd(MET)(D₂O)₂](NO₃)₂

a Coordination Chemistry Institute, State Key Lab of Coordination Chemistry, Nanjing University, Nanjing, 210093;
b Department of Chemistry, Iowa State University, Ames IA 50011, USA

Received Date: 27 June 1995

Fund Project: This work was supported by the National Natural Science Foundation of China.

cis-[Pd(met)(D₂O)₂]²⁺ promoted hydrolysis of AcMet-Gly was monitored by ¹H NMR spectroscopy.The observed rate constants,k_oba,strongly depend on the mole ratio of cis-[Pd(met)(D₂O)₂]²⁺ to AcMet-Gly.At least,one aqua ligand for each Pd(Ⅱ)is necessary for fast hydrolysis reaction observed.Two aqua ligands of each Pd(Ⅱ) make the reaction faster.
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