Citation: Jin Wang HUANG, Liang Nian JI, Yu Dong SU, He Zhcu WANG, A. K. Hsieh. THE PHOTOCHEMICAL SYNTHESIS OF THE PYRIDINE ADDUCT OF TETRAPHENYLPORPHYRINATORHODIUM(Ⅱ) AND THE MECHANISM OF PHOTOCHEMICAL REACTION[J]. Chinese Chemical Letters, ;1991, 2(4): 279-280. shu

THE PHOTOCHEMICAL SYNTHESIS OF THE PYRIDINE ADDUCT OF TETRAPHENYLPORPHYRINATORHODIUM(Ⅱ) AND THE MECHANISM OF PHOTOCHEMICAL REACTION

1.
Department of Chemistry, Department of Physics# , Zhongshan University, Guangzhou 510275;
2.
Department of Chemistry, National University of Singapor

Received Date: 3 December 1990

Fund Project: Project Supported by Science Research Foundation of Zhongshan University, National Natural Science Foundation of P. R. C^na and Resarch Fund of Royai Society of Chemistry

A new rhodium(Ⅱ) porphyrin complex was isolated by chromatography from the photochemical reaction of(μ—tetraphenylporphyrinato)bis[dicarbonylrhodium(Ⅰ)]with pyridine in benzene and has been characterized.From the results,the reaction mechanism is proposed.
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