Citation: ZHANG Jie, SHE Yongbo, LU Bin, ZHOU Yuliang, FU Kejian. A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM[J]. Chinese Journal of Polymer Science, ;1993, 11(4): 337-341. shu

A NEW METHOD ON THE CHEMICAL SYNTHESIS OF DOPED POLYPYRROLE INITIATED BY CuCl2-C2H5OH SYSTEM

ZHANG Jie ^{*，佘永柏，陆斌，周岳亮，博克坚} ,
SHE Yongbo ,
LU Bin ,
ZHOU Yuliang ,
FU Kejian

Received Date: 19 May 1992

Our objectives were to develop a new chemical method for the polymerization of pyrrole. CuCl2 dissolved in C2H5OH solvent is primarily used for the initiation polymerization of pyrrole. The polymers with different yield and conductivity were obtained by raring the initial concentration of Cu2+. The initial concentrations of Cu2+ varied from 1.2 × 10-4 mole to 6.48 × 10-3 mole Cu2+ with 2.16 × 10-2 mole pyrrole. The polypyrrole obtained was characterized with elemental analyzer, XPS, IR spectroscopy,Four-point probe and SEM.
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