Solvent-free Mechanochemical and Liquid-phase Reaction of [60]Fullerene with Ethyl 2-Diazopropionate

Yu Jin LI Ru Fang PENG You Cheng LIU Guan Wu WANG

引用本文: Yu Jin LI,  Ru Fang PENG,  You Cheng LIU,  Guan Wu WANG. Solvent-free Mechanochemical and Liquid-phase Reaction of [60]Fullerene with Ethyl 2-Diazopropionate[J]. Chinese Chemical Letters, 2004, 15(11): 1265-1268. shu
Citation:  Yu Jin LI,  Ru Fang PENG,  You Cheng LIU,  Guan Wu WANG. Solvent-free Mechanochemical and Liquid-phase Reaction of [60]Fullerene with Ethyl 2-Diazopropionate[J]. Chinese Chemical Letters, 2004, 15(11): 1265-1268. shu

Solvent-free Mechanochemical and Liquid-phase Reaction of [60]Fullerene with Ethyl 2-Diazopropionate

  • 基金项目:

    We are grateful for the financial support from the National Science Fund for Distinguished Young Scholars (20125205), "Hundred Talents Program" of Chinese Academy of Sciences, Anhui Natural Science Foundation (00045306), and Anhui Provincial Bureau of Personnel Affairs.

摘要: The solvent-free mechanochemical reaction and the liquid-phase reaction of C60 with ethyl 2-diazopropionate prepared in situ or preformed from alanine ethyl ester hydrochloride and sodium nitrite have been investigated. Methanofullerene 1 and fulleroids 2 and 3 from these reactions were obtained, meanwhile the pyrazoline intermediate was not observed. Fulleroids 2 and 3 can be converted to methanofullerene 1 in refluxing toluene.

English

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  709
  • HTML全文浏览量:  16
文章相关
  • 收稿日期:  2003-10-20
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章