Citation: Guo Ren YUE, Zheng Zhang. THE　REACTION　OF　p-NITROPHENYLSULFONYLACETONITRILE　WITH　α,β-UNSATURATED　ESTERS　AND　NITRILES[J]. Chinese Chemical Letters, ;1996, 7(4): 305-308. shu

THE　REACTION　OF　p-NITROPHENYLSULFONYLACETONITRILE　WITH　α,β-UNSATURATED　ESTERS　AND　NITRILES

Guo Ren YUE ^a ,
Zheng Zhang ^b

a Department of Chemistry, Zhangye Teachers' College, Zhangye, 734000
b Department of Chemistry, Nanjing University, Nanjing, 210093

Received Date: 16 August 1995

Michael addition and an unexpected tandem addition-rearrangement reaction occurred when p-nitrophenylsulfonylacetonitrile (1) reacted with α,β-unsaturated esters and nitriles (2a-f).Different products can be obtained depending on the particular reaction conditions chosen.All new produets (3 and 4,6) were characterized by spectroscopy.
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