Citation: Fu An KANG, Cheng Lie YIN. Asymmetric 1,3-Dipolar Cycloaddition of the Chiral Nitronic Esters with Acrylate[J]. Chinese Chemical Letters, ;1997, 8(12): 1019-1020. shu

Asymmetric 1,3-Dipolar Cycloaddition of the Chiral Nitronic Esters with Acrylate

Department of Chemiscy Beijing Normal Unthersho Beijing 100875

Received Date: 17 July 1997

Fund Project: Financial support provided by the National Natural Science Foundation of China, the Doctoral Program Foundation of the State Education Commission and the Allied Analysis Foundation of Beijing Zhongguancun is gratefully acknowledged.

Asymmetric 1,3-dipolar cycloaddition of the chiral nitronic esters with acrylate giving the enantiomerically pure novel chiral bisheterocyclic compounds is described.
1. [1]
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2. [2]
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3. [3]
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6. [6]
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11. [11]
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13. [13]
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14. [14]
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19. [19]
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