Citation: WANG Yuanshen, GUO Mingming. NMR STUDIES ON POLYETHER-POLYURETHANE ZWITTERIONOMERS——CHAIN STRUCTURE AND PHASE SEPARATION[J]. Chinese Journal of Polymer Science, ;1986, 4(1): 72-77. shu

NMR STUDIES ON POLYETHER-POLYURETHANE ZWITTERIONOMERS——CHAIN STRUCTURE AND PHASE SEPARATION

WANG Yuanshen ^{*，郭鸣明**} ,
GUO Mingming

Received Date: 31 May 1985

The 1H and 13C NMR spectra of polyether-polyurethancs (A) based on 4, 4'-diphenylmethanediisocyanate (MDI), N-methyl diethanolamine (MDEA), and polytetramethyleneoxide (PTMO)and the zwitterionomers derived from A with various degree of ionization was assigned by comparingwith model compounds. Phase separation of the samples was visualized through pulsed NMR investigations. The FID signals of these multiphase elastomers were recorded and decomposed by non-linear least squaresregression into fast Gaussian and slow exponential components associated with the hard,the soft and the interface respectively.Thus pulsed NMR gives both qualitative and quantitative information about the existence of multiphases and the relative amounts of materials in each phase.
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