Citation: Hua Yu QIU, Wan Yong MA, Guan Bin LI, Cong Hao DENG. The Isomeric Structures of H₂GeLiF, the Prototype Germylenoid[J]. Chinese Chemical Letters, ;1999, 10(6): 511-514. shu

The Isomeric Structures of H₂GeLiF, the Prototype Germylenoid

1.
Department of Chemical Engineering, Shandong Institute of Light Industry, Jinan 250100;
2.
Institute of Theoretical Chemistry, Shandong University, Jinan 250100

Received Date: 17 November 1998

Fund Project: Project supported by the National Natural Science Foundation of China (No. 29673026) and the Doctoral Foundation of the State Education Commission of China.

The structures of four isomeric forms of the model germylenoid, H₂GeLiF. have been examined by ab initio MO theory. The most stable structure is suggested to be the p-complex 1. The other three species, three-membered ring 2, σ-complex 3 and tetrahedron 4, are also local minima on the potential energy surface, but are higher in energy.
- Germylenoid,
- p-complex,
- ab initio
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