Citation: Bao Lin SONG, Yang CAO, De Zhong NIU, Zai Sheng LU, Cheng ZENG. THE SYNTHESIS AND CHARACTERIZATION OF THE COORDINATION COMPOUNDS OF Pt(Ⅱ) AND Ir(Ⅲ) WITH 2-MERCAPTOPYRIDINE-1-OXIDE AND ITS METHYL DERIVATIVES[J]. Chinese Chemical Letters, ;1990, 1(3): 263-264. shu

THE SYNTHESIS AND CHARACTERIZATION OF THE COORDINATION COMPOUNDS OF Pt(Ⅱ) AND Ir(Ⅲ) WITH 2-MERCAPTOPYRIDINE-1-OXIDE AND ITS METHYL DERIVATIVES

a Department of Chemistry Xuzhou Teacher's College Xuzhou 221009;
b Coordination Chemistry Institute Nanjing University Nanjing 210008

Received Date: 31 January 1990

Six coordination compounds of Pt(Ⅱ)L₂ and Ir(Ⅲ)L3 type(where L is PT^-, 3Me-PT^- or 4Me-PT^-) are reported here.Four coordination compounds of the latter two ligands have never been reported before, while PT^-'s were synthesized with H₂PtCl₆ and (NH₄)3IrCl₆ respectively, which were different from the methods of Davidson et al.¹ and Sterinbrec H².They were characterized by elemental analysis, UV, IR, ¹HNMR and molar conductance.Their structural formulas have beendetermined, and the mechanism of synthetic reaction has been discussed.
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