Citation: Feng Shou XIAO, Masaru ICHIKAWA, Atsushi FUKUOKA, D. F. SHRIVER. CATALYTIC PERFORMANCE OF MIXED-BIMETALLIC RUTHENIUM CARBONYL CLUSTERDERIVED CATALYSTS IN CO HYDROGENATION[J]. Chinese Chemical Letters, ;1991, 3(9): 707-708. shu

CATALYTIC PERFORMANCE OF MIXED-BIMETALLIC RUTHENIUM CARBONYL CLUSTERDERIVED CATALYSTS IN CO HYDROGENATION

a Catalysis Research Center Hokkaido University Sapporo 060 Japan;
b Department of Chemistry Jilin University Changchun 120023 China;
c Department of Chemistry Northwestern University Evanston IL 602083113 USA

Received Date: 24 July 1991

The bimetallic catalysts prepared from SiO₂-supported Ru-Co, Ru-Fe and Ru-Mo carbonyl clusters exhibited high yields and selectivities towards oxygenates such as C₁-C₅ from CO+H₂, in contrast to the catalysts prepared from homometallic and bimetallic Ru, Ru-Ni, Ru-Rh, Ru-Mn, and Ru-Cr carbonyl clusters.The FTIR investigation revealed that the 1584 cm^-1 species plays an important role in the formation of oxygenates in CO hydrogenation, which is possibly assigned to surface formyl species.
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