Citation: Jing Ru AN, Jin Ming LIN. MECHANISM OF ELECTROCHEMILUMINESCENCE OF THE NEW REAGENT 6-(2-HYDROXY-DIETHYLAMINOPHENYLAZO)-2, 3-DIHYDRO-1, 4-PHTHALAZINE-1, 4-DIONE CATALYZED BY SILVER (Ⅰ)[J]. Chinese Chemical Letters, ;1992, 3(4): 315-318. shu

MECHANISM OF ELECTROCHEMILUMINESCENCE OF THE NEW REAGENT 6-(2-HYDROXY-DIETHYLAMINOPHENYLAZO)-2, 3-DIHYDRO-1, 4-PHTHALAZINE-1, 4-DIONE CATALYZED BY SILVER (Ⅰ)

Jing Ru AN ,
Jin Ming LIN

Department of Chemistry Fuzhou University Fuzhou 350002

Received Date: 2 December 1991

The electrochemi luminescence of a new reagent 6-<2-hydroxy-4-diethylaminophenylazo>-2, 3-dihydro-1, 4-phthatazine-1, 4-dione in basic aqueous solution was studied. Trace amount of silver(I) showed significant effect on the efficiency of light emission of HDEA during a positive trigonometrical wave pulse was exerted on the electrodes In the present paper, the ecl spectra of HDEA have been measured. λ_max is 410 nm. The reaction of HDEA chemiluminescence and the circular voltammetry, ultraviolet-visible spectrometry for the system have been investigated. The possible mechanism of the ecl of HDEA-KCL-KOH-Ag(I) system has been proposed
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