Citation: Feng Yi LIU, Lian She FU, Jun WANG, Huan Rong LI, Hong Jie ZHANG. Hybrid Luminescent Films Obtained by Covalent Anchoring Terbium Complex to Silica-based Network[J]. Chinese Chemical Letters, ;2002, 13(10): 991-992. shu

Hybrid Luminescent Films Obtained by Covalent Anchoring Terbium Complex to Silica-based Network

Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 30 December 2001

Fund Project: We are grateful to the "973"-National Key Project for Fundamental Research of Rare Earth Functional Materials of China, The National Natural Science Foundation of China (No.29971030, No.20171043) for the financial suppprt of this work.

New monomer N-(4-carboxyphenyl)-NL-(propyltriethoxysilyl) urea (1) which acts as both a ligand for Tb³⁺ ion and a sol-gel precursor has been synthesized and characterized by ¹H NMR, and MS. Hybrid luminescent thin films consisting of organoterbium covalently bonded to a silica-based network have been obtained in situ via a sol-gel approach. Strong line emission of Tb³⁺ ion was observed from the hybrid luminescent films under UV excitation.
- Hybrid thin film,
- luminescence,
- sol-gel
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