Citation: LI Gui-Lian, LIU Guang-Zhen, HUANG Lei-Lei, LI Zhao-Xiao. A Novel 3D Cu(Ⅱ) Coordination Polymer Containing Mixed Ligands: Synthesis, Crystal Structure and Properties[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 942-946. shu

A Novel 3D Cu(Ⅱ) Coordination Polymer Containing Mixed Ligands: Synthesis, Crystal Structure and Properties

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Received Date: 4 December 2013
Available Online: 5 May 2014
Fund Project: the Foundation of Science and Technology of Henan Province (No. 112102310638) (No. 2011GGJS-153)

A novel compound, {[Cu₂(nbdc)₂(4,4'-bpy)₂(H₂O)₂]·2H₂O}_n (H₂nbdc=4-nitrobenzene-1,2-dicarboxylic acid, 4,4'-bpy=4,4'-bipyridine), was hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. The complex is of orthorhombic system, space group Pbcn with a=32.222(7), b=7.8503(16), c=28.389(6)Å, V=7181(3)Å³, D_c=1.720 g/cm³, M_r=929.74, Z=8, F(000)=3792, μ=1.273 mm^-1, the final R=0.0591 and wR=0.1378 for 4548 observed reflections with I>2σ(I). The compound exhibits a 3D self-penetrating framework with bcu net topology, in which the (4⁶·4⁸)-networks are joined by the H₂nbdc and 4,4'-bpy linkers.
- 4-nitrobenzene-1,2-dicarboxylic acid,
- hydrothermal synthesis,
- copper(Ⅱ) complex
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