Citation: Xiang Hong LIU, Xiao Guang ZHANG, Yue LI, Xiu Yan WANG, Nan Quan LOU. Mass Spectrometric Study of Clusters Produced by Laser Vaporization of Some Phosphates[J]. Chinese Chemical Letters, ;1997, 8(9): 805-806. shu

Mass Spectrometric Study of Clusters Produced by Laser Vaporization of Some Phosphates

State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Received Date: 7 April 1997

Fund Project: This work was under the project #29673044 supported by National Natural Science Foundation of China.

The clusters generated by direct laser vaporization of KH₂PO₄ and Cu₃(PO₄)₂ samples are studied by a TOF mass spectrometer.It is found that mainly the[K(KPO₃)_n] cluster series is generated from KH₂PO₄ sample and it demonstrates obvious magic numbers,which are n=3,6,9,12,15.Direct laser vaporization of Cu₃(PO₄)₂ sample produced[Cu(CuPO₃)_n] cluster series as well as other series with the same building block of (CuPO₃).
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