Citation: Tao Geng, Xiao-Guang Teng, Qiu-Xiao Li, Ya-Jie Jiang, Guo-Jin Li. Synthesis and properties of long-chain quaternary ammonium hydroxides[J]. Chinese Chemical Letters, ;2013, 24(6): 494-496. shu

Synthesis and properties of long-chain quaternary ammonium hydroxides

1.
China Research Institute of Daily Chemical Industry, Taiyuan 030001, China

Corresponding author: Tao Geng,
Received Date: 15 January 2013
Available Online: 19 March 2013

A series of long-chain quaternary ammonium hydroxides were synthesized from tertiary amines and confirmed by ¹H NMR and FTIR. Surface properties and pH of these surfactants were investigated. The critical micelle concentrations (CMC) of the synthesized quaternary ammonium hydroxides are lower than the conventional quaternary ammonium surfactants. The micelles shapes of these long-chain quaternary ammonium hydroxides in aqueous solution are spherical at a concentration of 0.1 mol/L. The pH values of the synthesized quaternary ammonium hydroxides are 12.25-12.51.
- Quaternary ammonium hydroxide,
- Surface activity,
- CMC,
- The pH value
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沈阳化工大学材料科学与工程学院沈阳 110142