Citation: Chang-Zhi Zhao, Jun-Yu Liang, Xiao-Lei Gu, Hui Liu. Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode[J]. Chinese Chemical Letters, ;2014, 25(2): 370-374. shu

Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode

1.
College of Chemistry & Molecular Engineering, Qingdao University of Science & Technology, Qingdao 266042, China

Corresponding author: Chang-Zhi Zhao,
Received Date: 28 August 2013
Available Online: 25 October 2013

The present study reports a sensitive electro-analytical method for the simultaneous determination of dihydroxybenzene isomers by using a thiadiazole film electrode, which was readily prepared by electropolymerization of 2,5-dimercapto-1,3,4-thiadiazole on a glassy carbon electrode with cyclic voltammetry. The functionalized electrode has a distinguishable and sensitive response to dihydroxybenzene isomers. Under the optimized conditions, the linear stripping peak currents showed good linear relationships with hydroquinone, catechol and resorcinol at concentration ranges 0.50-120, 0.50-110 and 1.00-110 μmol/L, and the detection limits are 0.1, 0.1 and 0.3 μmol/L, respectively. The proposed method is applicable to the simultaneous determination of dihydroxybenzene isomers in real samples with the relative standard deviations of less than 5.7% and the recovery rates of 95.6%-106%. The constructed electrode is characterized by simple preparation, good selectivity, and high sensitivity advantages.
- Electrochemical analysis,
- Dihydroxybenzene isomers,
- 2,5-Dimercapto-1,3,4-thiadiazole,
- Electropolymerization
1. [1]
  [1] K.J. Huang, S. Yu, L. Wang, T. Gan, M. Li, Simultaneous determination of hydroquinone, catechol and resorcinol based on graphene/cobalt hexacyanoferrate modified glassy carbon, electrode, Acta Chim. Sinica 70 (2012) 735-740.
2. [2]
  [2] X. Zhang, S. Duan, X. Xu, S. Xu, C. Zhou, Electrochemical behavior and simultaneous determination of dihydroxybenzene isomers at a functionalized SBA-15 mesoporous silica modified carbon paste electrode, Electrochim. Acta 56 (2011) 1981-1987.
3. [3]
  [3] H.S. Yin, Q.M. Zhang, Y.L. Zhou, et al., Electrochemical behavior of catechol, resorcinol and hydroquinone at graphene-chitosan composite film modified glassy carbon electrode and their simultaneous determination in water samples, Electrochim. Acta 56 (2011) 2748-2753.
4. [4]
  [4] D.W. Li, Y.T. Li, W. Song, Y.T. Long, Simultaneous determination of dihydroxybenzene isomers using disposable screen-printed electrode modified by multiwalled carbon nanotubes and gold nanoparticles, Anal. Methods 2 (2010) 837-843.
5. [5]
  [5] D.D. Zhang, Y.G. Peng, H.L. Qi, Q. Gao, C.X. Zhang, Application of multielectrode array modified with carbon nanotubes to simultaneous amperometric determination of dihydroxybenzene isomers, Sens. Actuators B 136 (2009) 113-121.
6. [6]
  [6] L. Han, X.L. Zhang, Simultaneous voltammetry determination of dihydroxybenzene isomers by nanogold modified electrode, Electroanalysis 21 (2009) 124-129.
7. [7]
  [7] J.P. Dong, X.M. Qu, L.J. Wang, C.J. Zhao, J.Q. Xu, Electrochemistry of nitrogen-doped carbon nanotubes (CNx) with different nitrogen content and its application in simultaneous determination of dihydroxybenzene isomers, Electroanalysis 20 (2008) 1981-1986.
8. [8]
  [8] P.H. Yang,W.Z. Wei, C.Y. Tao, J.X. Zeng, Simultaneous voltammetry determination of dihydroxybenzene isomers by poly-bromophenol blue/carbon nanotubes composite modified electrode, Bull. Environ. Contam. Toxicol. 79 (2007) 5-10.
9. [9]
  [9] P.H. Yang, W.Z. Wei, L. Yang, Simultaneous voltammetric determination of dihydroxybenzene isomers using a poly(acid chrome blue K) carbon nanotube composite electrode, Microchim. Acta 157 (2007) 229-235.
10. [10]
  [10] S. Cosnier, M. Holzinger, Electrosynthesized polymers for biosensing, Chem. Soc. Rev. 40 (2011) 2146-2156.
11. [11]
  [11] P. Kalimuthu, S.A. John, Electropolymerized film of functionalized thiadiazole on glassy carbon electrode for the simultaneous determination of ascorbic acid, dopamine and uric acid, Bioelectrochemistry 77 (2009) 13-18.
12. [12]
  [12] C.Z. Zhao, H. Liu, L. Wang, Simultaneous determination of Pb(Ⅱ) and Cd(Ⅱ) using an electrode modified with electropolymerized thiadiazole film, Anal. Methods 4 (2012) 3586-3592.
13. [13]
  [13] T. Tatsuma, Y. Yokoyama, D.A. Buttry, N. Oyama, Electrochemical polymerization and depolymerization of 2,5-dimercapto-1,3,4-thiadiazole. QCM and spectroscopic analysis, J. Phys. Chem. B 101 (1997) 7556-7562.
14. [14]
  [14] D.T. Harvey, Modern Analytical Chemistry, McGraw-Hill, New York, 2000, p. 151.
1. [1]
  Lingjun Sha , Bing Bo , Jiayu Li , Qi Liu , Ya Cao , Jing Zhao . Precise assessment of lung cancer-derived exosomes based on dual-labelled membrane interface. Chinese Chemical Letters, 2025, 36(4): 110109-. doi: 10.1016/j.cclet.2024.110109
2. [2]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
3. [3]
  Shuhui Li , Rongxiuyuan Huang , Yingming Pan . Electrochemical Synthesis of 2,5-Diphenyl-1,3,4-Oxadiazole: A Recommended Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(5): 357-365. doi: 10.12461/PKU.DXHX202407028
4. [4]
  Xiang-Da Zhang , Jian-Mei Huang , Xiaorong Zhu , Chang Liu , Yue Yin , Jia-Yi Huang , Yafei Li , Zhi-Yuan Gu . Auto-tandem CO₂ reduction by reconstructed Cu imidazole framework isomers: Unveiling pristine MOF-mediated CO₂ activation. Chinese Chemical Letters, 2025, 36(5): 109937-. doi: 10.1016/j.cclet.2024.109937
5. [5]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
6. [6]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
7. [7]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
8. [8]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
9. [9]
  Fengyu Zhang , Yali Liang , Zhangran Ye , Lei Deng , Yunna Guo , Ping Qiu , Peng Jia , Qiaobao Zhang , Liqiang Zhang . Enhanced electrochemical performance of nanoscale single crystal NMC811 modification by coating LiNbO₃. Chinese Chemical Letters, 2024, 35(5): 108655-. doi: 10.1016/j.cclet.2023.108655
10. [10]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
11. [11]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
12. [12]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
13. [13]
  Xubin Qian , Lei Xu , Xu Ge , Zhun Liu , Cheng Fang , Jianbing Wang , Junfeng Niu . Can perfluorooctanoic acid be effectively degraded using β-PbO₂ reactive electrochemical membrane?. Chinese Chemical Letters, 2024, 35(7): 109218-. doi: 10.1016/j.cclet.2023.109218
14. [14]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
15. [15]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
16. [16]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
17. [17]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
18. [18]
  Runze Liu , Yankai Bian , Weili Dai . Qualitative and quantitative analysis of Brønsted and Lewis acid sites in zeolites: A combined probe-assisted 1H MAS NMR and NH3-TPD investigation. Chinese Journal of Structural Chemistry, 2024, 43(4): 100250-100250. doi: 10.1016/j.cjsc.2024.100250
19. [19]
  Hai-Yang Song , Jun Jiang , Yu-Hang Song , Min-Hang Zhou , Chao Wu , Xiang Chen , Wei-Min He . Supporting-electrolyte-free electrochemical [2 + 2 + 1] annulation of benzo[d]isothiazole 1,1-dioxides, N-arylglycines and paraformaldehyde. Chinese Chemical Letters, 2024, 35(6): 109246-. doi: 10.1016/j.cclet.2023.109246
20. [20]
  Xueling Yu , Lixing Fu , Tong Wang , Zhixin Liu , Na Niu , Ligang Chen . Multivariate chemical analysis: From sensors to sensor arrays. Chinese Chemical Letters, 2024, 35(7): 109167-. doi: 10.1016/j.cclet.2023.109167

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(910)
HTML views(21)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142