Citation: Qun LIU, Kocienski PHILIP. A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES[J]. Chinese Chemical Letters, ;1991, 2(5): 353-356. shu

A NEW METHOD FOR THE PREPARATION OF PHENOLS AND ITS DERIVATIVES

Qun LIU ^a ,
Kocienski PHILIP ^b

a Department of Chemistry, Northeast Normal University, Changchun, 130024;
b Department of Chemistry, The University of Southampton, Southampton. S09 5. NH, U. K

Received Date: 17 December 1990

α-Oxo ketene dithioacetals 2 via 1,2-nucleophilie addition by methallyl magnesium chloride afforded corresponding alcohols (3). Treated with water or methanol and catalyzed by Lewis acid, the alcohols 3 were converted regiospecifically to substituted phenols 5'or related phenol methyl ethers 5 respectively. This reaction is a novel approach to the synthesis of phenols and their derivatives starting from non-aromatic precursors.
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