具有0D/2D界面的InOOH/ZnIn2S4空心球S型异质结用于增强光催化CO2转化性能

引用本文: 蔡佳星, 徐文迪, 迟浩强, 刘倩, 高娃, 史丽, 刘敬祥, 邹志刚, 周勇. 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能[J]. 物理化学学报, 2024, 40(11): 240700. doi: 10.3866/PKU.WHXB202407002 shu

Citation: Jiaxing Cai, Wendi Xu, Haoqiang Chi, Qian Liu, Wa Gao, Li Shi, Jingxiang Low, Zhigang Zou, Yong Zhou. Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion[J]. Acta Physico-Chimica Sinica, 2024, 40(11): 240700. doi: 10.3866/PKU.WHXB202407002 shu

具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能

蔡佳星 ^{1, †,} ,
徐文迪 ^{3, †,} ,
迟浩强 ^4, ,
刘倩 ^1, ,
高娃 ^{1,
,} ,
史丽 ^{3,
,} ,
刘敬祥 ^{1, 5,
,} ,
邹志刚 ^4, ,
周勇 ^{2, 4,
,}

1.
天津工业大学物理科学与技术学院, 天津 300387
2.
安徽工业大学化学与环境工程学院, 安徽芜湖 241000
3.
南京邮电大学有机电子与信息显示国家重点实验室, 先进材料研究所(IAM), 南京 210023
4.
南京大学物理学院, 江苏省纳米技术重点实验室, 生态材料与可再生能源研究中心, 固态微结构国家实验室, 先进微结构协同创新中心, 南京 210093
5.
Multidisciplinary Platform of Advanced Engineering, Chemical Engineering Discipline, School of Engineering, Monash University Malaysia, Bandar Sunway 47500, Selangor, Malaysia

通讯作者: 高娃, gaowa@tiangong.edu.cn; 史丽, iamlshi@njupt.edu.cn; 刘敬祥, jxlow@tiangong.edu.cn; 周勇, zhouyong1999@nju.edu.cn

基金项目:
国家重点研发计划 2022YFE0126500

国家重点研发计划 2018YFE0208500

国家自然科学基金委员会项目 21972065

国家自然科学基金委员会项目 22203046

国家自然科学基金委员会项目 22202152

江苏省科学基金会 BK20220006

合肥微尺度物理科学国家实验室 KF2020006

广东省创新创业团队引进项目 2019ZL08L101

中国高校发展基金 UDF01001159

南京邮电大学有机电子与信息显示国家重点实验室项目 GZR2023010003

南京邮电大学自然科学研究创业人才招聘基金 NY221128

摘要: S型异质结光催化剂因其能够同时促进光生载流子的分离，并优化光催化剂的还原和氧化能力，而被广泛应用于光催化CO₂转化中。尽管S型异质结具有巨大的潜力，但其光催化CO₂转化性能仍然有限，这主要是由于其界面光生载流子迁移缓慢和光利用效率差。本文报道了一种具有0D/2D接触界面的InOOH/ZnIn₂S₄空心球S型异质结，以提高光催化CO₂转化性能。具体来说，空心球结构可以允许入射光在光催化剂内进行多重反射，以增强光利用效率。此外，0D/2D接触界面可以促进光生载流子在InOOH/ZnIn₂S₄空心球S型异质结上的迁移速率。结合原位光照X射线光电子能谱表征和自由基捕获实验，确认了InOOH和ZnIn₂S₄上光生空穴和电子的空间分离，有利于高效利用光生载流子进行光催化CO₂转化。因此，优化后的InOOH/ZnIn₂S₄展示了比原始ZnIn₂S₄高出25.8倍的光催化CO₂转化性能。本工作展示了一种简单而有效的策略，用于提高S型异质结的界面光电荷载流子迁移和光利用效率。

关键词:

English

Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion

Jiaxing Cai ^{1, †,} ,
Wendi Xu ^{3, †,} ,
Haoqiang Chi ^4, ,
Qian Liu ^1, ,
Wa Gao ^{1,
,} ,
Li Shi ^{3,
,} ,
Jingxiang Low ^{1, 5,
,} ,
Zhigang Zou ^4, ,
Yong Zhou ^{2, 4,
,}

1.
School of Physical Science and Technology, Tiangong University, Tianjin 300387, China
2.
School of Chemical and Environmental Engineering, Anhui Polytechnic University, Wuhu 241000, Anhui Province, China
3.
State Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing 210023, China
4.
School of Physics, Jiangsu Key Laboratory of Nanotechnology, Eco-materials and Renewable Energy Research Center (ERERC), National Laboratory of Solid State Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
5.
Multidisciplinary Platform of Advanced Engineering, Chemical Engineering Discipline, School of Engineering, Monash University Malaysia, Bandar Sunway 47500, Selangor, Malaysia

Corresponding author: Email: gaowa@tiangong.edu.cn (G.W.); Email: iamlshi@njupt.edu.cn (S.L.); Email: jxlow@tiangong.edu.cn (J.L.); Email: zhouyong1999@nju.edu.cn (Z.Y.)

Received Date: 02 July 2024
Accepted Date: 05 August 2024
Revised Date: 05 August 2024
Available Online: 15 November 2024
Fund Project:
the National Key R & D Program of China

the National Key R & D Program of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

the National Natural Science Foundation of China

the Natural Science Foundation of Jiangsu Province

the Hefei National Laboratory for Physical Sciences at the Microscale

the Program for Guangdong Introducing Innovative and Entrepreneurial Team

the Chinese University Development Fund

the Project of State Key Laboratory of Organic Electronics and Information Displays, Nanjing University of Posts and Telecommunications

Natural Science Research Start-up Foundation of Recruiting Talents of Nanjing University of Posts and Telecommunications
^†These authors contributed equally to this work.

Abstract: S-scheme heterojunction system represents a highly efficient strategy for photocatalytic applications as it can simultaneously facilitate photogenerated charge carrier separation and enhance the reduction-oxidation potentials of the photocatalyst. Despite its gigantic potential, the photocatalytic CO₂ conversion efficiency of the S-scheme heterojunction remains limited mainly attributed to the sluggish interfacial charge carrier migration and poor light utilization efficiency. Herein, we prepare an InOOH/ZnIn₂S₄ hollow sphere S-scheme heterojunction with 0D/2D contact interface for enhancing photocatalytic CO₂ conversion performance. Specifically, the hollow sphere morphology can cause the multireflection of incident light within the photocatalyst leading to enhanced light absorption of the photocatalyst. In addition, the 0D/2D contact interface can facilitate the photogenerated charge carrier migration transfer over the InOOH/ZnIn₂S₄ S-scheme heterojunction. Furthermore, combining in situ irradiated X-ray photoelectron spectroscopy (ISI-XPS) characterization and radicals trapping test, it is affirmed the accumulation of photogenerated holes and electrons respectively on InOOH and ZnIn₂S₄, which is beneficial for the effective utilization of photogenerated charge carriers. As a result, the photocatalytic CO₂ conversion performance of the optimized InOOH/ZnIn₂S₄ is ca. 25.8 times higher than that of pristine ZnIn₂S₄. Our reported results demonstrate a facile yet effective strategy for enhancing the interfacial photogenerated charge carrier migration and light utilization efficiency of S-scheme heterojunction.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能

通讯作者: 高娃, gaowa@tiangong.edu.cn; 史丽, iamlshi@njupt.edu.cn; 刘敬祥, jxlow@tiangong.edu.cn; 周勇, zhouyong1999@nju.edu.cn

English

Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion

Corresponding author: Email: gaowa@tiangong.edu.cn (G.W.); Email: iamlshi@njupt.edu.cn (S.L.); Email: jxlow@tiangong.edu.cn (J.L.); Email: zhouyong1999@nju.edu.cn (Z.Y.)

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