超薄2D/2D NiPS3/C3N5异质结的界面工程促进光催化产氢

引用本文: 胡佳伟, 夏楷, 杨奥, 张志豪, 肖雯, 刘超, 张勤芳. 超薄2D/2D NiPS₃/C₃N₅异质结的界面工程促进光催化产氢[J]. 物理化学学报, 2024, 40(5): 230504. doi: 10.3866/PKU.WHXB202305043 shu

Citation: Jiawei Hu, Kai Xia, Ao Yang, Zhihao Zhang, Wen Xiao, Chao Liu, Qinfang Zhang. Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution[J]. Acta Physico-Chimica Sinica, 2024, 40(5): 230504. doi: 10.3866/PKU.WHXB202305043 shu

超薄2D/2D NiPS₃/C₃N₅异质结的界面工程促进光催化产氢

胡佳伟 ^1, ,
夏楷 ^1, ,
杨奥 ^1, ,
张志豪 ^1, ,
肖雯 ^1, ,
刘超 ^{1, 2,
,} ,
张勤芳 ^{1,
,}

1.
盐城工学院材料科学与工程学院, 江苏盐城 224051
2.
盐城工学院江苏省生态环境材料重点实验室, 江苏盐城 224051

通讯作者: 刘超, cliu@ycit.edu.cn; 张勤芳, qfangzhang@gmail.com

基金项目:
国家自然科学基金 51902282

国家自然科学基金 12274361

江苏高校青蓝工程

江苏省自然科学基金 BK20211361

江苏省高校自然科学研究项目 20KJA430004

江苏省生态环境材料重点实验室开放课题资助项目

摘要: 探索高效水分解光催化剂具有获得氢能源的巨大潜力。调控异质结界面可以有效地促进电荷载流子的分离和太阳能的利用，从而提高光催化活性。本工作使用了一种机械混合辅助自组装方法来构建NiPS₃ (NPS)纳米片(NSs)/C₃N₅ (CN) NSs (NPS/CN)异质结，即在二维(2D) CN NSs表面紧密沉积2D NPS NSs以形成2D/2D异质结构。在可见光下，通过在去离子水和海水中分解水生成氢气来评价样品的光催化性能。与CN NSs和NPS NSs相比，NPS/CN复合材料显示出较高的光催化产氢(PHE)活性，这是由于光捕获能力增加和异质结形成的协同作用所致。然而，过量的NPS NSs沉积在CN NSs表面会降低NPS/CN中CN NSs组分的光吸收，从而降低NPS/CN复合材料的PHE活性。这表明，NPS/CN复合材料要获得良好的光催化活性，需要两个组分之间适当的质量比。优化后的光催化剂(3-NPS/CN)具有良好的结构稳定性，在可见光下PHE效率最高，为47.71 μmol∙h⁻¹，是CN NSs的2385.50倍。此外，3-NPS/CN在海水中也表现出良好的PHE活性，反应速率为8.99 μmol∙h⁻¹。采用光电化学、稳态光致发光(PL)、时间分辨光致发光(TR-PL)、稳态表面光电压(SPV)和时间分辨表面光电压(TPV)技术研究了不同光催化剂上的电荷分离和迁移。根据表征结果提出了一种可能的PHE机理。在NPS/CN光催化剂中，由于CN NSs和NPS NSs之间的电位差和强的界面电子耦合，光生电子从CN NSs的导带迅速迁移到NPS NSs的导带。然后，聚积在NPS NSs组份导带上的光生电子可以有效地还原质子生成氢气分子。同时，在三乙醇胺(TEOA)分子存在下，CN NSs和NPS NSs的价带上的光生空穴被消耗。本研究提供了一种简单的2D/2D异质结构光催化剂制备方法，该方法对于构建高效二维异质结光催化剂在能源领域中的应用具有重要价值。

关键词:

English

Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution

Jiawei Hu ^1, ,
Kai Xia ^1, ,
Ao Yang ^1, ,
Zhihao Zhang ^1, ,
Wen Xiao ^1, ,
Chao Liu ^{1, 2,
,} ,
Qinfang Zhang ^{1,
,}

1.
School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China
2.
Jiangsu Provincial Key Laboratory of Eco-Environmental Materials, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, China

Corresponding author: Email: cliu@ycit.edu.cn (C.L.); Email: qfangzhang@gmail.com (Q.Z.)

Received Date: 22 May 2023
Accepted Date: 12 July 2023
Revised Date: 12 July 2023
Available Online: 15 May 2024
Fund Project:
the National Natural Science Foundation of China

the National Natural Science Foundation of China

Qinglan Project of Jiangsu of China

Natural Science Foundation of Jiangsu Province, China

College Natural Science Research Project of Jiangsu Province, China

Open Project of Jiangsu Provincial Key Laboratory of Eco-Environmental Materials, China

Abstract: This study focuses on exploring efficient photocatalysts for water splitting, which holds great potential for harnessing hydrogen (H₂) as a renewable energy source. Modulating the heterojunction interface is known to enhance charge carrier separation and solar energy utilization, thereby boosting photocatalytic activity. In this work, a mechanical mixing-assisted self-assembly approach was developed to construct a heterojunction between NiPS₃ (NPS) nanosheets (NSs) and C₃N₅ (CN) NSs. Specifically, two-dimensional (2D) NPS NSs were tightly deposited on 2D CN NSs surface to gain a 2D/2D heterostructure. The photocatalytic performance of the synthesized photocatalysts was determined by their ability to generate H₂ through water splitting, both in deionized (DI) water and seawater, under visible light. The resulting NPS NSs/CN NSs (NPS/CN) composites possessed boosted photocatalytic hydrogen evolution (PHE) activity related to CN NSs and NPS NSs. This improvement was assigned to the synergistic effect of increased light-harvesting capacity and heterojunction formation. Nevertheless, an excessive amount of deposited NPS NSs on the surface of CN NSs was found to reduce the light absorption of the CN NSs component in the NPS/CN composites, resulting in decreased PHE activity. Therefore, it was determined that an appropriate mass ratio between the two components is necessary to achieve excellent photocatalytic activity for the NPS/CN composites. The optimized photocatalyst, referred to as 3-NPS/CN, demonstrated the highest visible-light-driven PHE efficiency of 47.71 μmol∙h⁻¹, which was 2385.50 times higher than that of CN NSs. Moreover, 3-NPS/CN also exhibited excellent PHE activity in seawater, with a rate of 8.99 μmol∙h⁻¹. The photoelectrochemical, steady-state photoluminescence (PL), time-resolved PL (TR-PL), steady-state surface photovoltage (SPV) and time-resolved surface photovoltage (TPV) techniques were performed to investigate the charge separation and migration behaviors of various photocatalysts. Based on the characterization results, our group proposed a reasonable PHE mechanism. In the NPS/CN photocatalysts, photo-induced electrons rapidly migrated from the conduction band (CB) of CN NSs to the CB of NPS NSs due to the potential difference and strong interfacial electronic coupling between the two materials. The photogenerated electrons accumulated on the CB of the NPS NSs component efficiently reduced protons to generate H₂ molecules. Concurrently, photogenerated holes on the valence band (VB) of CN NSs and NPS NSs were consumed with the assistance of triethanolamine (TEOA) molecules. This study presents a facile method for fabricating 2D/2D heterostructured photocatalysts, which hold promise for efficient and robust implementation in energy applications.

Key words:

1. [1]
  Gao, Y.; Xu, B.; Cherif, M.; Yu, H.; Zhang, Q.; Vidal, F.; Wang, X.; Ding, F.; Sun, Y.; Ma, D.; et al. Appl. Catal. B: Environ. 2020, 279, 119403. doi: 10.1016/j.apcatb.2020.119403
2. [2]
  Liu, C.; Zhang, Q.; Zou, Z. J. Mater. Sci. Technol. 2023, 139, 167. doi: 10.1016/j.jmst.2022.08.030
3. [3]
  Fujishima, A.; Honda, K. Nature 1972, 238, 37. doi: 10.1038/238037a0
4. [4]
  Tong, Z.; Yang, D.; Xiao, T.; Tian, Y.; Jiang, Z. Chem. Eng. J. 2015, 260, 117. doi: 10.1016/j.cej.2014.08.072
5. [5]
  Fu, C.; Wu, T.; Sun, G.; Yin, G.; Wang, C.; Ran, G.; Song, Q. Appl. Catal. B: Environ. 2023, 323, 122196. doi: 10.1016/j.apcatb.2022.122196
6. [6]
  Liu, C.; Zhang, Y.; Wu, J.; Dai, H.; Ma, C.; Zhang, Q.; Zou, Z. J. Mater. Sci. Technol. 2022, 114, 81. doi: 10.1016/j.jmst.2021.12.003
7. [7]
  Gao, Z.; Chen, K.; Wang, L.; Bai, B.; Liu, H.; Wang, Q. Appl. Catal. B: Environ. 2020, 268, 118462. doi: 10.1016/j.apcatb.2019.118462
8. [8]
  Qin, Y.; Li, H.; Lu, J.; Feng, Y.; Meng, F.; Ma, C.; Yan, Y.; Meng, M. Appl. Catal. B: Environ. 2020, 277, 119254. doi: 10.1016/j.apcatb.2020.119254
9. [9]
  Lin, B.; Li, H.; An, H.; Hao, W.; Wei, J.; Dai, Y.; Ma, C.; Yang, G. Appl. Catal. B: Environ. 2018, 220, 542. doi: 10.1016/j.apcatb.2017.08.071
10. [10]
  Yin, H.; Yuan, C.; Lv, H.; Zhang, K.; Chen, X.; Zhang, Y.; Zhang, Y. Powder Technol. 2023, 413, 118083. doi: 10.1016/j.powtec.2022.118083
11. [11]
  Wang, H.; Li, M.; Lu, Q.; Cen, Y.; Zhang, Y.; Yao, S. ACS Sustain. Chem. Eng. 2019, 7, 625. doi: 10.1021/acssuschemeng.8b04182
12. [12]
  Huang, L.; Liu, Z.; Chen, W.; Cao, D.; Zheng, A. J. Mater. Chem. A 2018, 6, 7168. doi: 10.1039/c8ta01458b
13. [13]
  Teng, M.; Shi, J.; Qi, H.; Shi, C.; Wang, W.; Kang, F.; Eqi, M.; Huang, Z. J. Colloid Interface Sci. 2022, 609, 592. doi: 10.1016/j.jcis.2021.11.060
14. [14]
  Sun, D.; Zhang, X.; Shi, A.; Quan, C.; Xiao, S.; Ji, S.; Zhou, Z.; Li, X.; Chi, F.; Niu, X. Appl. Surf. Sci. 2022, 601, 154186. doi: 10.1016/j.apsusc.2022.154186
15. [15]
  Li, K.; Cai, W.; Zhang, Z.; Xie, H.; Zhong, Q.; Qu, H. Chem. Eng. J. 2022, 435, 135017. doi: 10.1016/j.cej.2022.135017
16. [16]
  Meng, Q.; Yang, X.; Wu, L.; Chen, T.; Li, Y.; He, R.; Zhu, W.; Zhu, L.; Duan, T. J. Hazard. Mater. 2022, 422, 126912. doi: 10.1016/j.jhazmat.2021.126912
17. [17]
  Wang, R.; Zhang, K.; Zhong, X.; Jiang, F. RSC Adv. 2022, 12, 24026. doi: 10.1039/d2ra03874a
18. [18]
  Wu, B.; Sun, T.; Liu, N.; Lu, L.; Zhang, R.; Shi, W.; Cheng, P. ACS Appl. Mater. Interfaces 2022, 14, 26742. doi: 10.1021/acsami.2c04729
19. [19]
  Liu, D.; Yao, J.; Chen, S.; Zhang, J.; Li, R.; Peng, T. Appl. Catal. B: Environ. 2022, 318, 121822. doi: 10.1016/j.apcatb.2022.121822
20. [20]
  Shi, J.; Wang, W.; Teng, M.; Kang, F.; E'qi, M.; Huang, Z. J. Colloid Interface Sci. 2022, 608, 954. doi: 10.1016/j.jcis.2021.10.027
21. [21]
  Xiong, Z.; Liang, Y.; Yang, J.; Yang, G.; Jia, J.; Sa, K.; Zhang, X.; Zeng, Z. Sep. Purif. Technol. 2023, 306, 122522. doi: 10.1016/j.seppur.2022.122522
22. [22]
  Zhang, X.; Zhao, X.; Wu, D.; Jing, Y.; Zhou, Z. Adv. Sci. 2016, 3, 1600062. doi: 10.1002/advs.201600062
23. [23]
  Wang, J.; Li, X.; Wei, B.; Sun, R.; Yu, W.; Hoh, H. Y.; Xu, H.; Li, J.; Ge, X.; Chen, Z.; et al. Adv. Funct. Mater. 2020, 30, 1908708. doi: 10.1002/adfm.201908708
24. [24]
  Wang, F.; Shifa, T. A.; He, P.; Cheng, Z.; Chu, J.; Liu, Y.; Wang, Z.; Wang, F.; Wen, Y.; Liang, L.; et al. Nano Energy 2017, 40, 673. doi: 10.1016/j.nanoen.2017.09.017
25. [25]
  Shifa, T. A.; Wang, F.; Cheng, Z.; He, P.; Liu, Y.; Jiang, C.; Wang, Z.; He, J. Adv. Funct. Mater. 2018, 28, 1800548. doi: 10.1002/adfm.201800548
26. [26]
  Gusmao, R.; Sofer, Z.; Sedmidubsky, D.; Huber, S.; Pumera, M. ACS Catal. 2017, 7, 8159. doi: 10.1021/acscatal.7b02134
27. [27]
  Cheng, Z.; Shifa, T. A.; Wang, F.; Gao, Y.; He, P.; Zhang, K.; Jiang, C.; Liu, Q.; He, J. Adv. Mater. 2018, 30, 1707433. doi: 10.1002/adma.201707433
28. [28]
  Barua, M.; Ayyub, M. M.; Vishnoi, P.; Pramoda, K.; Rao, C. N. R. J. Mater. Chem. A 2019, 7, 22500. doi: 10.1039/c9ta06044h
29. [29]
  Jenjeti, R. N.; Kumar, R.; Austeria, M. P.; Sampath, S. Sci. Rep. 2018, 8, 8586. doi: 10.1038/s41598-018-26522-1
30. [30]
  Chittari, B. L.; Park, Y.; Lee, D.; Han, M.; MacDonald, A. H.; Hwang, E.; Jung, J. Phys. Rev. B 2016, 94, 184428. doi: 10.1103/PhysRevB.94.184428
31. [31]
  Chu, J.; Wang, F.; Yin, L.; Lei, L.; Yan, C.; Wang, F.; Wen, Y.; Wang, Z.; Jiang, C.; Feng, L.; et al. Adv. Funct. Mater. 2017, 27, 1701342. doi: 10.1002/adfm.201701342
32. [32]
  Fang, L.; Xie, Y.; Guo, P.; Zhu, J.; Xiao, S.; Sun, S.; Zi, W.; Zhao, H. Sustain. Energy Fuels 2021, 5, 2537. doi: 10.1039/d1se00110h
33. [33]
  Ran, J.; Zhang, H.; Fu, S.; Jaroniec, M.; Shan, J.; Xia, B.; Qu, Y.; Qu, J.; Chen, S.; Song, L.; et al. Nat. Commun. 2022, 13, 4600. doi: 10.1038/s41467-022-32256-6
34. [34]
  Li, S.; Cai, M.; Liu, Y.; Zhang, J.; Wang, C.; Zang, S.; Li, Y.; Zhang, P.; Li, X. Org. Chem. Front. 2022, 9, 2479. doi: 10.1039/D2QI00317A
35. [35]
  Zhang, Q.; Gu, H.; Wang, X.; Li, L.; Zhang, J.; Zhang, H.; Li, Y. -F.; Dai, W. -L. Appl. Catal. B: Environ. 2021, 298, 120632. doi: 10.1016/j.apcatb.2021.120632
36. [36]
  Liu, C.; Xiao, W.; Yu, G.; Wang, Q.; Hu, J.; Xu, C.; Du, X.; Xu, J.; Zhang, Q.; Zou, Z. J. Colloid Interface Sci. 2023, 640, 851. doi: 10.1016/j.jcis.2023.02.137
37. [37]
  Han, L.; Peng, C.; Huang, J.; Wang, S.; Zhang, X.; Chen, H.; Yang, Y. Rsc Adv. 2021, 11, 36166. doi: 10.1039/d1ra07275g
38. [38]
  Zhang, J.; Jing, B.; Tang, Z.; Ao, Z.; Xia, D.; Zhu, M.; Wang, S. Appl. Catal. B: Environ. 2021, 289, 120023. doi: 10.1016/j.apcatb.2021.120023
39. [39]
  Kumar, P.; Vahidzadeh, E.; Thakur, U. K.; Kar, P.; Alam, K. M.; Goswami, A.; Mahdi, N.; Cui, K.; Bernard, G. M.; Michaelis, V. K.; et al. J. Am. Chem. Soc. 2019, 141, 5415. doi: 10.1021/jacs.9b00144
40. [40]
  孙志聪, 罗二桂, 孟庆磊, 王显, 葛君杰, 刘长鹏, 邢巍. 物理化学学报, 2022, 38, 2003035. doi: 10.3866/PKU.WHXB202003035Sun, Z.; Luo, E.; Meng, Q.; Wang, X.; Ge, J.; Liu, C.; Xing, W. Acta Phys. -Chim. Sin. 2022, 38, 2003035. doi: 10.3866/PKU.WHXB202003035
41. [41]
  Wang, J.; Wang, T.; Shi, X.; Wu, J.; Xu, Y.; Ding, X.; Yu, Q.; Zhang, K.; Zhou, P.; Jiang, Z. J. Mater. Chem. C 2019, 7, 14625. doi: 10.1039/c9tc04722k
42. [42]
  Zhang, J.; Tao, H.; Wu, S.; Yang, J.; Zhu, M. Appl. Catal. B: Environ. 2021, 296, 120372. doi: 10.1016/j.apcatb.2021.120372
43. [43]
  Li, S.; Wang, C.; Cai, M.; Liu, Y.; Dong, K.; Zhang, J. J. Colloid Interface Sci. 2022, 624, 219. doi: 10.1016/j.jcis.2022.05.151
44. [44]
  Zhang, G.; Wang, Z.; He, T.; Wu, J.; Zhang, J.; Wu, J. Chem. Eng. J. 2022, 442, 136309. doi: 10.1016/j.cej.2022.136309
45. [45]
  Liu, C.; Han, Z.; Feng, Y.; Dai, H.; Zhao, Y.; Han, N.; Zhang, Q.; Zou, Z. J. Colloid Interface Sci. 2021, 583, 58. doi: 10.1016/j.jcis.2020.09.018
46. [46]
  孙涛, 李晨曦, 鲍钰鹏, 樊君, 刘恩周. 物理化学学报, 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009Sun, T.; Li, C.; Bao, Y.; Fan, J.; Liu, E. Acta Phys. -Chim. Sin. 2023, 39, 2212009. doi: 10.3866/PKU.WHXB202212009
47. [47]
  Che, H.; Wang, J.; Gao, X.; Chen, J.; Wang, P.; Liu, B.; Ao, Y. J. Colloid Interface Sci. 2022, 627, 739. doi: 10.1016/j.jcis.2022.07.080
48. [48]
  Zhan, X.; Zheng, Y.; Li, B.; Fang, Z.; Yang, H.; Zhang, H.; Xu, L.; Shao, G.; Hou, H.; Yang, W. Chem. Eng. J. 2022, 431, 134053. doi: 10.1016/j.cej.2021.134053
49. [49]
  Zhao, L.; Lei, S.; Tang, C.; Tu, Q.; Rao, L.; Liao, H.; Zeng, W.; Xiao, Y.; Cheng, B. J. Colloid Interface Sci. 2022, 616, 401. doi: 10.1016/j.jcis.2022.02.089
50. [50]
  Vedhanarayanan, B.; Chiu, C. -C.; Regner, J.; Sofer, Z.; Seetha Lakshmi, K. C.; Lin, J. -Y.; Lin, T. -W. Chem. Eng. J. 2022, 430, 132649. doi: 10.1016/j.cej.2021.132649
51. [51]
  Mane, G. P.; Talapaneni, S. N.; Lakhi, K. S.; Ilbeygi, H.; Ravon, U.; Al-Bahily, K.; Mori, T.; Park, D. -H.; Vinu, A. Angew. Chem. Int. Ed. 2017, 56, 8481. doi: 10.1002/anie.201702386
52. [52]
  Bai, J.; Chen, W.; Hao, L.; Shen, R.; Zhang, P.; Li, N.; Li, X. Chem. Eng. J. 2022, 447, 137488. doi: 10.1016/j.cej.2022.137488
53. [53]
  Sun, H.; Shi, Y.; Shi, W.; Guo, F. Appl. Surf. Sci. 2022, 593, 153281. doi: 10.1016/j.apsusc.2022.153281
54. [54]
  Chen, K.; Shi, Y.; Shu, P.; Luo, Z.; Shi, W.; Guo, F. Chem. Eng. J. 2023, 454, 140053. doi: 10.1016/j.cej.2022.140053
55. [55]
  Yu, G.; Zhang, Y.; Du, X.; Wu, J.; Liu, C.; Zou, Z. J. Colloid Interface Sci. 2022, 623, 205. doi: 10.1016/j.jcis.2022.05.040
56. [56]
  熊壮, 侯乙东, 员汝胜, 丁正新, 王伟俊, 汪思波. 物理化学学报, 2022, 38, 2111021. doi: 10.3866/PKU.WHXB202111021Xiong, Z; Hou, Y.; Yuan, R.; Ding, Z.; Ong, W. J.; Wang, S. Acta Phys. -Chim. Sin. 2022, 38, 2111021. doi: 10.3866/PKU.WHXB202111021
57. [57]
  郁桂云, 胡丰献, 程伟伟, 韩字童, 刘超, 戴勇. 物理化学学报, 2020, 36, 1911016. doi: 10.3866/PKU.WHXB201911016Yu, G.; Hu, F.; Cheng, W.; Han, Z.; Liu, C.; Dai, Y. Acta Phys. -Chim. Sin. 2020, 36, 1911016. doi: 10.3866/PKU.WHXB201911016
58. [58]
  蔡晓燕, 杜家豪, 钟光明, 张一鸣, 毛梁, 娄在祝. 物理化学学报, 2023, 39, 2302017. doi: 10.3866/PKU.WHXB202302017Cai, X.; Du, J.; Zhong, G.; Zhang, Y.; Mao, L.; Lou, Z. Acta Phys. -Chim. Sin. 2023, 39, 2302017. doi: 10.3866/PKU.WHXB202302017
59. [59]
  Cai, M.; Liu, Y.; Wang, C.; Lin, W.; Li, S. Sep. Purif. Technol. 2023, 304, 122401. doi: 10.1016/j.seppur.2022.122401
60. [60]
  Liu, C.; Xu, Q.; Zhang, Q.; Zhu, Y.; Ji, M.; Tong, Z.; Hou, W.; Zhang, Y.; Xu, J. J. Mater. Sci. 2019, 54, 2458. doi: 10.1007/s10853-018-2990-0
61. [61]
  谢垚, 张启涛, 孙宏丽, 滕镇远, 苏陈良. 物理化学学报, 2023, 39, 2301001. doi: 10.3866/PKU.WHXB202301001Xie, Y.; Zhang, Q.; Sun, H.; Teng, Z.; Su, C. Acta Phys. -Chim. Sin. 2023, 39, 2301001. doi: 10.3866/PKU.WHXB202301001
62. [62]
  Liu, C.; Xiao, W.; Liu, X.; Wang, Q.; Hu, J.; Zhang, S.; Xu, J.; Zhang, Q.; Zou, Z. J. Mater. Sci. Technol. 2023, 161, 123. doi: 10.1016/j.jmst.2023.04.007
63. [63]
  Liu, C.; Feng, Y.; Han, Z.; Sun, Y.; Wang, X.; Zhang, Q.; Zou, Z. Chin. J. Catal. 2021, 42, 164. doi: 10.1016/S1872-2067(20)63608-7
64. [64]
  Dang, X.; Xie, M.; Dai, F.; Guo, J.; Liu, J.; Lu, X. J. Mater. Chem. A 2021, 9, 14888. doi: 10.1039/D1TA02052H
65. [65]
  Zhang, X.; Hu, K.; Zhang, X.; Ali, W.; Li, Z.; Qu, Y.; Wang, H.; Zhang, Q.; Jing, L. Appl. Surf. Sci. 2019, 492, 125. doi: 10.1016/j.apsusc.2019.06.189
66. [66]
  Wang, J.; Qin, C.; Wang, H.; Chu, M.; Zada, A.; Zhang, X.; Li, J.; Raziq, F.; Qu, Y.; Jing, L. Appl. Catal. B: Environ. 2018, 221, 459. doi: 10.1016/j.apcatb.2017.09.042
67. [67]
  Li, L.; Zhang, R.; Lin, Y.; Wang, D.; Xie, T. Chem. Eng. J. 2023, 453, 139970. doi: 10.1016/j.cej.2022.139970
68. [68]
  刘珊池, 王凯, 杨梦雪, 靳治良. 物理化学学报, 2022, 38, 2109023. doi: 10.3866/PKU.WHXB202109023Liu, S.; Wang, K.; Yang, M.; Jin, Z. Acta Phys. -Chim. Sin. 2022, 38, 2109023. doi: 10.3866/PKU.WHXB202109023
69. [69]
  Guo, S.; Li, Y.; Xue, C.; Sun, Y.; Wu, C.; Shao, G.; Zhang, P. Chem. Eng. J. 2021, 419, 129213. doi: 10.1016/j.cej.2021.129213
70. [70]
  Cheng, C.; Zhang, J.; Zeng, R.; Xing, F.; Huang, C. Appl. Catal. B: Environ. 2022, 310, 121321. doi: 10.1016/j.apcatb.2022.121321
71. [71]
  Zheng, J.; Lei, Z. Appl. Catal. B: Environ. 2018, 237, 1. doi: 10.1016/j.apcatb.2018.05.060

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 233
HTML全文浏览量: 9

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

超薄2D/2D NiPS₃/C₃N₅异质结的界面工程促进光催化产氢

通讯作者: 刘超, cliu@ycit.edu.cn; 张勤芳, qfangzhang@gmail.com

English

Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution

Corresponding author: Email: cliu@ycit.edu.cn (C.L.); Email: qfangzhang@gmail.com (Q.Z.)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处