Citation: Kun ZHU, Jin-Xia YANG, Ye-Yan QIN, Yuan-Gen YAO. Three Novel Luminescent Zinc(II) Compounds Constructed by Employing Mixed-ligand Strategy[J]. Chinese Journal of Structural Chemistry, ;2021, 40(9): 1152-1160. doi: 10.14102/j.cnki.0254–5861.2011–3129 shu

Three Novel Luminescent Zinc(II) Compounds Constructed by Employing Mixed-ligand Strategy

Kun ZHU ^{a, b} ,
Jin-Xia YANG ^a ,
Ye-Yan QIN ^a ,
Yuan-Gen YAO ^a,,

a.
Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy Sciences, Beijing 100039, China

Corresponding author: Yuan-Gen YAO, yyg@fjirsm.ac.cn
Received Date: 1 February 2021
Accepted Date: 18 March 2021

Fund Project: the National Key R & D Program of China 2017YFB0307301the National Key R & D Program of China 2017YFA0206802the Strategic Priority Research Program of the Chinese Academy of Sciences XDA21020800the Science and Technology Service Network Initiative KFJ-STS-QYZD-048the NSF of China 21703247the NSF of China 21701172the Science Foundation of Fujian Province 2018J05029the Science Foundation of Fujian Province 2019J05156the Science Foundation of Fujian Province 2019H0053Guizhou Province [2018]2193

Figures(6)

Three novel coordination polymers, [Zn(suc)(o-bix)]_n (1), [Zn(suc)(m-bix)·H₂O]_n (2) and [Zn₂(suc)₂(p-bix)₂·4H₂O]_n (3) (H₂suc = succinic acid, o-bix = 1, 2-bis(imidazol-1-ylmethyl)-benzene, m-bix = 1, 3-bis(imidazol-1-ylmethyl)-benzene, p-bix = 1, 4-bis(imidazol-1-ylmethyl)-benzene), have been synthesized and structurally characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction, and single-crystal X-ray diffraction. These three coordination polymers present various structures originated from auxiliary N-donor ligands with different configurations. Compound 1 shows a 2D network with 4⁴-sql topology. Compound 2 exhibits an infinite chain, and the adjacent chains are extended into a 2D sheet by π-π stacking interactions. Changing the conformation of the N-donor ligand leads to 3 featuring a 3D framework with a novel 4-connected (6⁵·8) topology. In addition, the solid-state photoluminescent properties of compounds 1~3 are investigated.
- zinc(II) compounds,
- hydrothermal reaction,
- aliphatic dicarboxylates,
- mix-ligand,
- luminescence
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