Citation: Shi YANG, Hong JIANG, Wen-Qiang ZHANG, Xian-Hui TANG, Yao JIN, Yan LIU. Synthesis, Structure, and Characterization of a Novel Coordination Polymer with Polythreading Feature[J]. Chinese Journal of Structural Chemistry, ;2021, 40(3): 343-348. doi: 10.14102/j.cnki.0254–5861.2011–2877 shu

Synthesis, Structure, and Characterization of a Novel Coordination Polymer with Polythreading Feature

School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules and State Key Laboratory of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, China

Corresponding author: Yan LIU, liuy@sjtu.edu.cn
Received Date: 14 May 2020
Accepted Date: 29 June 2020

Fund Project: the National Science Foundation of China 91956124the National Science Foundation of China 21875136the National Key Basic Research Program of China 2016YFA0203400Shanghai Rising-Star Program 19QA1404300

Figures(5)

A novel coordination polymer 1 with formula of Zn₂(BDC)₂(TPPA) was built from 1, 4-dicarboxybenzene (H₂BDC), tris(4-(pyridin-3-yl)phenyl)amine (TPPA), and Zn(II) ion. It was characterized by single-crystal and powder X-ray diffraction, Fourier-transform infrared spectra (FT-IR), thermal gravimetric analysis (TGA), and UV-vis. 1 crystallizes in triclinic space group P\begin{document}$ \overline 1 $\end{document} with a = 14.589, b = 14.606, c = 16.108 Å, α = 115.635^o, β = 90.328^o, γ = 114.662^o, V = 2738.6 Å³, Z = 2, M_r = 935.52 g/mol, D_c = 1.134 g/cm³, F(000) = 956, GOOF = 1.062, the final R = 0.0685 and wR = 0.1817 for 7701 observed reflections with (I > 2σ(I)), and R = 0.0717 and wR = 0.1843 for all data. In 1, Zn(II) is coordinated with H₂BDC to form a 2D square grid, and TPPA ligands were arranged above and beneath the 2D layer. Two neighbor layers are interpenetrated each other by π-π interactions to generate a polythreading framework structure. Moreover, the photoluminescence of 1 was also studied.
- coordination polymer,
- polythreading,
- single crystal,
- photoluminescence
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