Citation: Zhenyang Lin. A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics[J]. Chinese Journal of Structural Chemistry, ;2024, 43(5): 100254. doi: 10.1016/j.cjsc.2024.100254 shu

A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics

Zhenyang Lin

A novel classification scheme for inorganic cluster compounds is presented based on the characteristics of their electronic structures. In the classification scheme, five distinct categories have been introduced, including Jellium clusters, Wadian clusters, electron-precise clusters, π-donor ligated metal-metal bonded clusters, and antiferromagnetically coupled high-spin metal clusters.
- Inorganic cluster compounds,
- Structure and bonding,
- Electron counting rules,
- Superatomic clusters
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