Citation: Yuting Fu, Haoran Wang, Nan Li, Lujiao Mao, Xusheng Wang, Qipeng Li, Jinjie Qian. Pt inclusion effect on Ni-ABDC-derived PtNi-carbon nanomaterials for hydrogen evolution[J]. Chinese Chemical Letters, ;2025, 36(10): 110890. doi: 10.1016/j.cclet.2025.110890 shu

Pt inclusion effect on Ni-ABDC-derived PtNi-carbon nanomaterials for hydrogen evolution

Yuting Fu ^a ,
Haoran Wang ^a ,
Nan Li ^a ,
Lujiao Mao ^a ,
Xusheng Wang ^c ,
Qipeng Li ^{b, *,} ,
Jinjie Qian ^{a, *,}

a.
Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
b.
College of Chemistry and Chemical Engineering, Zhaotong University, Zhaotong 657000, China
c.
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China

qpli@ztu.edu.cn

jinjieqian@wzu.edu.cn

Received Date: 13 January 2025
Revised Date: 18 January 2025
Accepted Date: 20 January 2025
Available Online: 20 January 2025

Figures(5)

The development of cost-effective and high-efficiency catalysts for sustainable hydrogen production through electrocatalytic hydrogen evolution reaction (HER) is crucial yet remains challenging. In this work, we synthesized two types of bimetallic PtNi nanoparticles embedded in N-doped porous carbons derived from Ni-ABDC (5-aminoisophthalate) using both in-situ and ex-situ Pt inclusion methods. The in-situ Pt doping notably disrupted the effective growth of Ni-ABDC nanostrips owing to strong interactions between Pt and ABDC, resulting in an amorphous nanostructure. The optimized Pt_inNi-NC exhibited remarkable HER performance with a low overpotential of 29 mV at 10 mA/cm², a Tafel slope of 47.4 mV/dec, and a current retention of 91.2% after 200 h in 1.0 mol/L KOH solution, surpassing the performance of Ni-NC, Pt_exNi-NC, and Pt/C. This research demonstrates the rational design and preparation of transition metal-based coordination polymer-derived metal-carbon nanomaterials with low Pt loading, emphasizing their considerable potential in energy conversion and storage technologies.
- Coordination polymer,
- Pt inclusion,
- PtNi nanoparticle,
- Carbon nanomaterials,
- Hydrogen evolution reaction
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