Citation: Hongtao Wang, Yingzhang Shi, Jiayi Guo, Shuzhao Sun, Wenda Zhang, Zhiwen Wang, Yujie Song, Dongpeng Yan. CdS clusters induced defect on NH₂−MIL-125(Ti) nanosheets for improving photocatalytic synthesis of N-benzylidene benzylamine[J]. Chinese Chemical Letters, ;2025, 36(10): 110779. doi: 10.1016/j.cclet.2024.110779 shu

CdS clusters induced defect on NH₂−MIL-125(Ti) nanosheets for improving photocatalytic synthesis of N-benzylidene benzylamine

Hongtao Wang ^a ,
Yingzhang Shi ^a ,
Jiayi Guo ^a ,
Shuzhao Sun ^a ,
Wenda Zhang ^a ,
Zhiwen Wang ^a ,
Yujie Song ^{a, *,} ,
Dongpeng Yan ^{b, c, **,}

a.
School of Chemistry and Chemical Engineering, Hainan University, Haikou 570228, China
b.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China
c.
The Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai, Yantai 264000, China

^**

songyujie@hainanu.edu.cn

yandp@bnu.edu.cn

Received Date: 2 June 2024
Revised Date: 29 October 2024
Accepted Date: 18 December 2024
Available Online: 19 December 2024

Figures(6)

Utilizing interfacial interaction between different components of a heterojunction to induce defect formation may be an interesting approach for improving the catalytic performance. Here, introducing 3 nm CdS clusters (S) on NH₂−MIL-125(Ti) nanosheets (NMT-NS) to construct the heterojunction catalysts (S_x/NMT-NS) can induce the generation of abundant defects and Ti³⁺ sites due to the lattice distortion of NMT-NS and the transfer of interfacial charges. These defects and Ti³⁺ sites can chemisorb benzyl alcohol (BZO) molecules through a C-O⋯Ti coordination while capture and activate O₂ molecules from air. Furthermore, Z-scheme heterojunction between CdS clusters and NMT-NS optimizes the transfer and separation of photogenerated electrons-holes, thus accelerating the production of ^∙O₂^-. Therefore, S_1.8/NMT-NS achieves a highly efficient conversion of benzylamine (BZA) (> 99%) and BZO to N-benzylidene benzylamine (N-BZA) in air atmosphere under visible light, with a selectivity of 99%. Finally, a photocatalytic mechanism involving the activation of reactants molecule and the transfer of photogenerated carriers is propounded at molecular level.
- Photocatalysis,
- Nanosheets,
- Defect,
- Coupling reaction,
- Coordination activation
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CdS clusters induced defect on NH2−MIL-125(Ti) nanosheets for improving photocatalytic synthesis of N-benzylidene benzylamine

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通讯作者: 陈斌, bchen63@163.com

CdS clusters induced defect on NH₂−MIL-125(Ti) nanosheets for improving photocatalytic synthesis of N-benzylidene benzylamine