Citation: Siyang Xue, Chen Cheng, Jieqiong Kang, Kaixuan Zheng, Adela Jing Li, Renli Yin. Oxygen vacancies-rich BiOBr bridged direct electron transfer with peroxymonosulfate for integrating superoxide radical and singlet oxygen on selective pollutants degradation[J]. Chinese Chemical Letters, ;2025, 36(10): 110776. doi: 10.1016/j.cclet.2024.110776 shu

Oxygen vacancies-rich BiOBr bridged direct electron transfer with peroxymonosulfate for integrating superoxide radical and singlet oxygen on selective pollutants degradation

Siyang Xue ^{a, 1} ,
Chen Cheng ^{a, 1} ,
Jieqiong Kang ^a ,
Kaixuan Zheng ^{b, *,} ,
Adela Jing Li ^a ,
Renli Yin ^{a, *,}

a.
Guangdong Laboratory for Lingnan Modern Agriculture, Guangdong Provincial Key Laboratory of Agricultural & Rural Pollution Abatement and Environmental Safety, College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China
b.
State Environmental Protection Key Laboratory of Environmental Pollution Health Risk Assessment, South China Institute of Environmental Science, Ministry of Ecological Environment, Guangzhou 510655, China

kaixuan_zh18@163.com

yinrenli@scau.edu.cn

Received Date: 8 October 2024
Revised Date: 4 November 2024
Accepted Date: 18 December 2024
Available Online: 19 December 2024

Figures(4)

Bisphenol A (BPA) has threatened ecological safety and human health due to its endocrine disrupting effect and widely diffused in the environment. Peroxymonosulfate (PMS) based on oxidation technology exhibits good potential for environmental remediation whereas the highly efficient activator needs to be developed. Herein, the BiOBr (BOB) was synthesized to efficiently activate PMS to remove 95.6% of BPA within 60 min. The observed rate constant of BPA removal in BOB/PMS system is 0.049 min^-1, which is 60 and 148 times to that of the BOB and PMS processes separately and 129 times to the compared BiOCl (BOC)/PMS system, respectively. Comparison experiments and analytic methods demonstrate that BOB with a larger content of oxygen vacancies (O_v) can act as the bridge of electron transfer between Bi³⁺/Bi⁴⁺ with PMS to enhance the activation ability for PMS, resulting in the production of abundant reactive oxygen species (O₂^•− and ¹O₂). Additionally, the breakdown processes of BPA and the toxicity of its byproducts were uncovered, and the potential for actual water treatment was evaluated to confirm the detoxification, efficiency, stability and practical use of the BOB/PMS system for eliminating BPA. This study may widen the application of traditional semiconductors and develop the cost-effective PMS activation methods for environmental remediation.
- Peroxymonosulfate,
- BiOBr,
- Oxygen vacancy,
- Bisphenol A,
- Selective degradation
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