Citation: Siyang Xue, Chen Cheng, Jieqiong Kang, Kaixuan Zheng, Adela Jing Li, Renli Yin. Oxygen vacancies-rich BiOBr bridged direct electron transfer with peroxymonosulfate for integrating superoxide radical and singlet oxygen on selective pollutants degradation[J]. Chinese Chemical Letters, ;2025, 36(10): 110776. doi: 10.1016/j.cclet.2024.110776 shu

Oxygen vacancies-rich BiOBr bridged direct electron transfer with peroxymonosulfate for integrating superoxide radical and singlet oxygen on selective pollutants degradation

Siyang Xue ^{a, 1} ,
Chen Cheng ^{a, 1} ,
Jieqiong Kang ^a ,
Kaixuan Zheng ^{b, *,} ,
Adela Jing Li ^a ,
Renli Yin ^{a, *,}

a.
Guangdong Laboratory for Lingnan Modern Agriculture, Guangdong Provincial Key Laboratory of Agricultural & Rural Pollution Abatement and Environmental Safety, College of Natural Resources and Environment, South China Agricultural University, Guangzhou 510642, China
b.
State Environmental Protection Key Laboratory of Environmental Pollution Health Risk Assessment, South China Institute of Environmental Science, Ministry of Ecological Environment, Guangzhou 510655, China

kaixuan_zh18@163.com

yinrenli@scau.edu.cn

Received Date: 8 October 2024
Revised Date: 4 November 2024
Accepted Date: 18 December 2024
Available Online: 19 December 2024

Figures(4)

Bisphenol A (BPA) has threatened ecological safety and human health due to its endocrine disrupting effect and widely diffused in the environment. Peroxymonosulfate (PMS) based on oxidation technology exhibits good potential for environmental remediation whereas the highly efficient activator needs to be developed. Herein, the BiOBr (BOB) was synthesized to efficiently activate PMS to remove 95.6% of BPA within 60 min. The observed rate constant of BPA removal in BOB/PMS system is 0.049 min^-1, which is 60 and 148 times to that of the BOB and PMS processes separately and 129 times to the compared BiOCl (BOC)/PMS system, respectively. Comparison experiments and analytic methods demonstrate that BOB with a larger content of oxygen vacancies (O_v) can act as the bridge of electron transfer between Bi³⁺/Bi⁴⁺ with PMS to enhance the activation ability for PMS, resulting in the production of abundant reactive oxygen species (O₂^•− and ¹O₂). Additionally, the breakdown processes of BPA and the toxicity of its byproducts were uncovered, and the potential for actual water treatment was evaluated to confirm the detoxification, efficiency, stability and practical use of the BOB/PMS system for eliminating BPA. This study may widen the application of traditional semiconductors and develop the cost-effective PMS activation methods for environmental remediation.
- Peroxymonosulfate,
- BiOBr,
- Oxygen vacancy,
- Bisphenol A,
- Selective degradation
1. [1]
  M.G. Antoniou, A.A. de la Cruz, D.D. Dionysiou, Appl. Catal. B: Environ. 96 (2010) 290–298. doi: 10.1016/j.apcatb.2010.02.013
2. [2]
  Y. Bao, W. Lee, C. Guan, et al., Sep. Purif. Technol. 276 (2021) 119203. doi: 10.1016/j.seppur.2021.119203
3. [3]
  Y. Bu, H. Li, W. Yu, et al., Environ. Sci. Technol. 55 (2021) 2110–2120. doi: 10.1021/acs.est.0c07274
4. [4]
  H. Cai, J. Zou, J. Lin, et al., Chem. Eng. J. 429 (2022) 132438. doi: 10.1016/j.cej.2021.132438
5. [5]
  Y. Cai, Y. Xu, J. Xiang, et al., J. Environ. Sci. 137 (2024) 321–332. doi: 10.1016/j.jes.2023.01.005
6. [6]
  Y. Yang, Z. Song, W. Ren, et al., Appl. Catal. B: Environ. 359 (2024) 124470. doi: 10.1016/j.apcatb.2024.124470
7. [7]
  Z. Song, Y. Zhang, Y. Yang, et al., Environ. Sci. Ecotechnol. 22 (2024) 100452. doi: 10.1016/j.ese.2024.100452
8. [8]
  Y. Cao, J. Yao, T. Š. Knudsen, et al., Chemosphere 312 (2023) 137169. doi: 10.1016/j.chemosphere.2022.137169
9. [9]
  H. Chen, Z. Han, S. Cao, et al., Chem. Eng. J. 453 (2023) 139660. doi: 10.1016/j.cej.2022.139660
10. [10]
  L. Chen, X. Zuo, L. Zhou, et al., Chem. Eng. J. 345 (2018) 364–374. doi: 10.1016/j.cej.2018.03.169
11. [11]
  N. Chen, D. Lee, H. Kang, et al., J. Environ. Chem. Eng. 10 (2022) 107654. doi: 10.1016/j.jece.2022.107654
12. [12]
  Y. Chen, X. Bai, Y. Ji, D. Chen, J. Hazard. Mater. 441 (2023) 129912. doi: 10.1016/j.jhazmat.2022.129912
13. [13]
  Y. Chen, S. Lan, M. Zhu, Chin. Chem. Lett. 32 (2021) 2052–2056. doi: 10.1016/j.cclet.2020.11.016
14. [14]
  X. Cheng, H. Guo, Y. Zhang, X. Wu, Y. Liu, Water Res. 113 (2017) 80–88. doi: 10.1016/j.watres.2017.02.016
15. [15]
  D. Colón, E.J. Weber, J.L. Anderson, Environ. Sci. Technol. 42 (2008) 6538–6543. doi: 10.1021/es8004249
16. [16]
  D. Cui, H. He, W. Xie, et al., J. Hazard. Mater. 465 (2024) 133155. doi: 10.1016/j.jhazmat.2023.133155
17. [17]
  T. Das, B. Verma, Chem. Phys. Lett. 739 (2020) 136947. doi: 10.1016/j.cplett.2019.136947
18. [18]
  X. Dou, Y. Chen, H. Shi, Chem. Eng. J. 431 (2022) 134054. doi: 10.1016/j.cej.2021.134054
19. [19]
  F. Ghanbari, M. Moradi, Chem. Eng. J. 310 (2017) 41–62. doi: 10.1016/j.cej.2016.10.064
20. [20]
  S. Guo, H. Wang, W. Yang, et al., Appl. Catal. B: Environ. 262 (2020) 118250. doi: 10.1016/j.apcatb.2019.118250
21. [21]
  P. Intaphong, A. Phuruangrat, K. Karthik, et al., J. Inorg. Organomet. Polym. Mater. 30 (2020) 714–721. doi: 10.1007/s10904-019-01259-0
22. [22]
  N. Li, R. Li, X. Duan, et al., Environ. Sci. Technol. 55 (2021) 16163–16174. doi: 10.1021/acs.est.1c06244
23. [23]
  W. Li, W. Li, K. He, et al., J. Hazard. Mater. 432 (2022) 128719. doi: 10.1016/j.jhazmat.2022.128719
24. [24]
  Z. Li, W. Mao, L. Yao, et al., J. Hazard. Mater. 424 (2022) 127549. doi: 10.1016/j.jhazmat.2021.127549
25. [25]
  K. Lin, K.Z. Zhang, Chem. Eng. J. 313 (2017) 1320–1327. doi: 10.1016/j.cej.2016.11.025
26. [26]
  L. Long, C. Bai, X. Zhou, et al., Sep. Purif. Technol. 297 (2022) 121432. doi: 10.1016/j.seppur.2022.121432
27. [27]
  X. Long, C. Feng, D. Ding, et al., J. Hazard. Mater. 418 (2021) 126357. doi: 10.1016/j.jhazmat.2021.126357
28. [28]
  D. Lopez-Rodriguez, D. Franssen, J. Bakker, A. Lomniczi, A.S. Parent, Nat. Rev. Endocrinol. 17 (2021) 83–96. doi: 10.1038/s41574-020-00436-3
29. [29]
  X. Luo, Y. Liu, C. Yang, et al., J. Eur. Ceram. Soc. 35 (2015) 2073–2081. doi: 10.1016/j.jeurceramsoc.2015.01.024
30. [30]
  M.V. Maffini, B.S. Rubin, C. Sonnenschein, A.M. Soto, Mol. Cell. Endocrinol. 254–255 (2006) 179–186.
31. [31]
  F. Qiu, Y. Pan, L. Wang, et al., Sep. Purif. Technol. 330 (2024) 125139. doi: 10.1016/j.seppur.2023.125139
32. [32]
  X. Qiu, Y. Zhao, C. Li, R. Jin, E. Mutabazi, Chem. Eng. J. 475 (2023) 146234. doi: 10.1016/j.cej.2023.146234
33. [33]
  S. Sifakis, V.P. Androutsopoulos, A.M. Tsatsakis, D.A. Spandidos, Environ. Toxicol. Phar. 51 (2017) 56–70. doi: 10.1016/j.etap.2017.02.024
34. [34]
  A. Takdastan, B. Kakavandi, M. Azizi, M. Golshan, Chem. Eng. J. 331 (2018) 729–743. doi: 10.1016/j.cej.2017.09.021
35. [35]
  K. Hou, G. Zhu, Y. Feng, Y. Liu, X. Quan, Chin. Chem. Lett. 35 (2024) 108704. doi: 10.1016/j.cclet.2023.108704
36. [36]
  H. Wang, B. Liao, T. Lu, Y. Ai, G. Liu, J. Hazard. Mater. 385 (2020) 121552. doi: 10.1016/j.jhazmat.2019.121552
37. [37]
  H. Wang, Z. Long, R. Chen, et al., Sep. Purif. Technol. 331 (2024) 125598. doi: 10.1016/j.seppur.2023.125598
38. [38]
  H. Wang, X. Wang, Y. Zhou, et al., Sep. Purif. Technol. 307 (2023) 122771. doi: 10.1016/j.seppur.2022.122771
39. [39]
  M. Wang, B. Guo, J. Zhan, et al., Chem. Phys. Lett. 807 (2022) 140093. doi: 10.1016/j.cplett.2022.140093
40. [40]
  X. Wang, G. Xu, Y. Tu, et al., Chem. Eng. J. 411 (2021) 128456. doi: 10.1016/j.cej.2021.128456
41. [41]
  Y. Wang, D. Cao, X. Zhao, Chem. Eng. J. 328 (2017) 1112–1121. doi: 10.1016/j.cej.2017.07.042
42. [42]
  Y. Wei, H. Su, Y. Zhang, et al., Chem. Eng. J. 375 (2019) 121971. doi: 10.1016/j.cej.2019.121971
43. [43]
  J. Xie, J. Zhao, J. Han, et al., J. Colloid Interf. Sci. 652 (2023) 1588–1596. doi: 10.1016/j.jcis.2023.08.194
44. [44]
  L. Xu, X. Wu, C. Li, et al., J. Clean. Prod. 394 (2023) 136275. doi: 10.1016/j.jclepro.2023.136275
45. [45]
  J. Yang, T. Xie, Y. Mei, et al., Appl. Catal. B: Environ. 339 (2023) 123149. doi: 10.1016/j.apcatb.2023.123149
46. [46]
  L. Ye, X. Jin, C. Liu, et al., Appl. Catal. B: Environ. 187 (2016) 281–290. doi: 10.1016/j.apcatb.2016.01.044
47. [47]
  S. Zhu, X. Li, J. Kang, X. Duan, S. Wang, Environ. Sci. Technol. 53 (2019) 307–315. doi: 10.1021/acs.est.8b04669
48. [48]
  J. Yan, J. Peng, L. Lai, et al., Environ. Sci. Technol. 52 (2018) 14302–14310. doi: 10.1021/acs.est.8b03340
49. [49]
  M. Liu, H. Qin, H. Xu, et al., Sep. Purif. Technol. 307 (2023) 122711. doi: 10.1016/j.seppur.2022.122711
1. [1]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
2. [2]
  Jin ZHANG , Yuting WANG , Bin YU , Yuxin ZHONG , Yufeng ZHANG . Corn straw-derived carbon/BiOBr composite: Synthesis and photocatalytic degradation performance for rhodamine B. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1397-1408. doi: 10.11862/CJIC.20250028
3. [3]
  Shuo Li , Xinran Liu , Yongjie Zheng , Jun Ma , Shijie You , Heshan Zheng . Effective peroxydisulfate activation by CQDs-MnFe₂O₄@ZIF-8 catalyst for complementary degradation of bisphenol A by free radicals and non-radical pathways. Chinese Chemical Letters, 2024, 35(5): 108971-. doi: 10.1016/j.cclet.2023.108971
4. [4]
  Shenghui Tu , Anru Liu , Hongxiang Zhang , Lu Sun , Minghui Luo , Shan Huang , Ting Huang , Honggen Peng . Oxygen vacancy regulating transition mode of MIL-125 to facilitate singlet oxygen generation for photocatalytic degradation of antibiotics. Chinese Chemical Letters, 2024, 35(12): 109761-. doi: 10.1016/j.cclet.2024.109761
5. [5]
  Jinshu Huang , Zhuochun Huang , Tengyu Liu , Yu Wen , Jili Yuan , Song Yang , Hu Li . Modulating single-atom Co and oxygen vacancy coupled motif for selective photodegradation of glyphosate wastewater to circumvent toxicant residue. Chinese Chemical Letters, 2025, 36(5): 110179-. doi: 10.1016/j.cclet.2024.110179
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Xiaofan ZHANG , Yu DUAN , Meijie SHI , Nan LU , Renhong LI , Xiaoqing YAN . Z-scheme Co₃O₄/BiOBr heterojunction for efficient photoreduction CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1878-1888. doi: 10.11862/CJIC.20250079
8. [8]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
9. [9]
  Huiyuan Deng , Na Zhao , Junjie You , Zhicheng Pan , Bo Xing , Yuling Ye , Bo Lai , Yuxi Wang , Tongrui Lu , Xiaonan Liu . Removal of bisphenol a through peroxymonosulfate activation with N-doped graphite carbon spheres coated cobalt nanoparticles catalyst: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(8): 110650-. doi: 10.1016/j.cclet.2024.110650
10. [10]
  Mengmeng Ao , Jian Wei , Chuan-Shu He , Heng Zhang , Zhaokun Xiong , Yonghui Song , Bo Lai . Insight into the activation of peroxymonosulfate by N-doped copper-based carbon for efficient degradation of organic pollutants: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(1): 109882-. doi: 10.1016/j.cclet.2024.109882
11. [11]
  Jijoe Samuel Prabagar , Kumbam Lingeshwar Reddy , Dong-Kwon Lim . Visible-light responsive gold nanoparticle and nano-sized Bi2O3-x sheet heterozygote structure for efficient photocatalytic conversion of N2 to NH3. Chinese Journal of Structural Chemistry, 2025, 44(4): 100564-100564. doi: 10.1016/j.cjsc.2025.100564
12. [12]
  Qinwei Lu , Jinjie Lu , Juying Lei , Xubiao Luo , Yanbo Zhou . Cyclodextrin-boosted photocatalytic oxidation for efficient bisphenol A removal. Chinese Chemical Letters, 2025, 36(3): 110017-. doi: 10.1016/j.cclet.2024.110017
13. [13]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
14. [14]
  Guo Yang , Kai Li , Hanshi Qu , Jianbing Zhu , Chunyu Ru , Meiling Xiao , Wei Xing , Changpeng Liu . Tailoring OH* adsorption strength on Ni/NbO_x for boosting alkaline hydrogen oxidation reaction via oxygen vacancy. Chinese Chemical Letters, 2025, 36(7): 110150-. doi: 10.1016/j.cclet.2024.110150
15. [15]
  Jiayi Guo , Liangxiong Ling , Qinwei Lu , Yi Zhou , Xubiao Luo , Yanbo Zhou . Degradation of chloroxylenol by CoS_x activated peroxomonosulfate: Role of cobalt-sulfur ratio. Chinese Chemical Letters, 2025, 36(4): 110380-. doi: 10.1016/j.cclet.2024.110380
16. [16]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
17. [17]
  Ming-Zhen Li , Yang Zhang , Kun Li , Ya-Nan Shang , Yi-Zhen Zhang , Yu-Jiao Kan , Zhi-Yang Jiao , Yu-Yuan Han , Xiao-Qiang Cao . In situ regeneration of catalyst for Fenton-like degradation by photogenerated electron transportation: Characterization, performance and mechanism comparison. Chinese Chemical Letters, 2025, 36(1): 109885-. doi: 10.1016/j.cclet.2024.109885
18. [18]
  Yu Yao , Jinqiang Zhang , Yantao Wang , Kunsheng Hu , Yangyang Yang , Zhongshuai Zhu , Shuang Zhong , Huayang Zhang , Shaobin Wang , Xiaoguang Duan . Nitrogen-rich carbon for catalytic activation of peroxymonosulfate towards green synthesis. Chinese Chemical Letters, 2024, 35(11): 109633-. doi: 10.1016/j.cclet.2024.109633
19. [19]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
20. [20]
  Tianjun Ni , Hui Zhang , Liping Zhou , Roujie Ma , Yanyu Wang , Zhijun Yang , Dan Luo , Nithima Khaorapapong , Xingtao Xu , Yusuke Yamauchi , Dong Liu . Atomic cobalt catalysts on 3D interconnected g-C₃N₄ support for activation of peroxymonosulfate: The importance of Co-N coordination effect. Chinese Chemical Letters, 2025, 36(9): 110659-. doi: 10.1016/j.cclet.2024.110659

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(78)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142