Citation: Junyi Yu, Yin Cheng, Anhong Cai, Xianfeng Huang, Qingrui Zhang. Synthetic Cu(Ⅲ) from copper plating wastewater for onsite decomplexation of Cu(Ⅱ)- and Ni(Ⅱ)-organic complexes[J]. Chinese Chemical Letters, ;2025, 36(2): 110549. doi: 10.1016/j.cclet.2024.110549 shu

Synthetic Cu(Ⅲ) from copper plating wastewater for onsite decomplexation of Cu(Ⅱ)- and Ni(Ⅱ)-organic complexes

Junyi Yu ^a ,
Yin Cheng ^a ,
Anhong Cai ^a ,
Xianfeng Huang ^{a, *,} ,
Qingrui Zhang ^{b, *,}

a.
National and Local Joint Engineering Research Center for Ecological Treatment Technology of Urban Water Pollution, College of Life and Environmental Science, Wenzhou University, Wenzhou 325035, China
b.
State Key Laboratory of Metastable Materials Science and Technology, Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, China

xianfeng_huang@wzu.edu.cn

zhangqr@ysu.edu.cn

Received Date: 8 January 2024
Revised Date: 11 October 2024
Accepted Date: 13 October 2024
Available Online: 14 October 2024

Figures(6)

Herein, the Cu(Ⅲ) synthesized from copper plating effluent was developed for the first time to evaluate the onsite degradation performance of heavy metal complexes in the wastewater, thus achieving the purpose of "treating waste with waste". The results indicated that synthetic Cu(Ⅲ) presented the excellent decomplexation performance for Cu(Ⅱ)/Ni(Ⅱ)-organic complexes. The removal efficiency of Cu(Ⅱ)/Ni(Ⅱ)-EDTA significantly increased with increasing Cu(Ⅲ) dosage, and the degradation of Cu(Ⅱ)/Ni(Ⅱ)-EDTA by synthetic Cu(Ⅲ) system displayed highly pH-dependent reactivity. The radical quencher experiments confirmed that Cu(Ⅲ) direct oxidation were mainly involved in the degradation of Cu(Ⅱ)-EDTA. Additionally, the continuous decarboxylation process was proven to be the main degradation pathway of Cu(Ⅱ)-EDTA in Cu(Ⅲ) system. The coexisting substances (SO₄²⁻, Cl⁻ and fulvic acids) showed little impacts at low level for the removal of Cu(Ⅱ)/Ni(Ⅱ)-EDTA, while retarded the degradation of Cu(Ⅱ)-EDTA slightly at high level, which features high selective oxidation. Encouragingly, it was also effective to remove Cu(Ⅱ)/Ni(Ⅱ)-EDTA from in treating actual Cu/Ni-containing wastewater through synthetic Cu(Ⅲ) treatment.
- Copper plating wastewater,
- Cu(Ⅲ),
- Decomplexation,
- Treating waste with waste,
- Selectivity
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