Citation: Qi Xia, Ke Yan, Ke Jin, Yang Wu, Yanan Fu, Ding Chen, Huixin Chen, Hongjun Yue. Interface design of tea stem-derived micropore carbon enables high-performance Na-Se batteries[J]. Chinese Chemical Letters, ;2025, 36(10): 110406. doi: 10.1016/j.cclet.2024.110406 shu

Interface design of tea stem-derived micropore carbon enables high-performance Na-Se batteries

Qi Xia ^{a, b, 1} ,
Ke Yan ^{b, c, 1} ,
Ke Jin ^{e, f, 1} ,
Yang Wu ^d ,
Yanan Fu ^{b, c} ,
Ding Chen ^g ,
Huixin Chen ^{a, b, g, *,} ,
Hongjun Yue ^{a, b, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China
c.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
d.
Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Institute of Materials Physical Chemistry, Huaqiao University, Xiamen 361021, China
e.
Sinopec Maoming Petrochemical Co., Ltd., Maoming 525000, China
f.
Guangdong Provincial Key Laboratory of Advanced Green Lubricating Materials, Maoming 525000, China
g.
State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, China

chenhuixin@fjirsm.ac.cn

hjyue@fjirsm.ac.cn

Received Date: 8 August 2024
Accepted Date: 3 September 2024
Available Online: 4 September 2024

Figures(4)

Na-Se batteries have caught tremendous attention because of natural abundant of element sodium and their high volumetric energy density (2530 Wh/L). However, the low utilization ratio of Se is the main obstacle for practical application. Herein, an advanced Se-based electrode is designed and prepared by using tea stem-derived micropore carbon matrix (TSC) as Se host and coating TSC/Se with cyclic polyacrylonitrile (cPAN). TSC/Se/cPAN electrode shows rate capacity of 318.3 mAh/g at 2 C (1 C=675 mA/g) and great discharge capacity of 420.6 mAh/g after 300 cycles at 0.2 C. The impressive electrochemical performance is mainly ascribed to the interface design of cPAN coating, resulting in the enhanced electronic conductivity of whole electrode and high ratio of robust inorganic salt NaCl in CEI film. The TSC/Se/cPANNVP full cell also exhibits great discharge capacity of 556.6 mAh/g after 55 cycles at 0.1 C.
- Interface design,
- Cyclic polyacrylonitrile,
- Biomass recycling,
- CEI analysis,
- Na-Se batteries
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