Citation: Qi Xia, Ke Yan, Ke Jin, Yang Wu, Yanan Fu, Ding Chen, Huixin Chen, Hongjun Yue. Interface design of tea stem-derived micropore carbon enables high-performance Na-Se batteries[J]. Chinese Chemical Letters, ;2025, 36(10): 110406. doi: 10.1016/j.cclet.2024.110406 shu

Interface design of tea stem-derived micropore carbon enables high-performance Na-Se batteries

Qi Xia ^{a, b, 1} ,
Ke Yan ^{b, c, 1} ,
Ke Jin ^{e, f, 1} ,
Yang Wu ^d ,
Yanan Fu ^{b, c} ,
Ding Chen ^g ,
Huixin Chen ^{a, b, g, *,} ,
Hongjun Yue ^{a, b, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China
c.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
d.
Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Institute of Materials Physical Chemistry, Huaqiao University, Xiamen 361021, China
e.
Sinopec Maoming Petrochemical Co., Ltd., Maoming 525000, China
f.
Guangdong Provincial Key Laboratory of Advanced Green Lubricating Materials, Maoming 525000, China
g.
State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, China

chenhuixin@fjirsm.ac.cn

hjyue@fjirsm.ac.cn

Received Date: 8 August 2024
Accepted Date: 3 September 2024
Available Online: 4 September 2024

Figures(4)

Na-Se batteries have caught tremendous attention because of natural abundant of element sodium and their high volumetric energy density (2530 Wh/L). However, the low utilization ratio of Se is the main obstacle for practical application. Herein, an advanced Se-based electrode is designed and prepared by using tea stem-derived micropore carbon matrix (TSC) as Se host and coating TSC/Se with cyclic polyacrylonitrile (cPAN). TSC/Se/cPAN electrode shows rate capacity of 318.3 mAh/g at 2 C (1 C=675 mA/g) and great discharge capacity of 420.6 mAh/g after 300 cycles at 0.2 C. The impressive electrochemical performance is mainly ascribed to the interface design of cPAN coating, resulting in the enhanced electronic conductivity of whole electrode and high ratio of robust inorganic salt NaCl in CEI film. The TSC/Se/cPANNVP full cell also exhibits great discharge capacity of 556.6 mAh/g after 55 cycles at 0.1 C.
- Interface design,
- Cyclic polyacrylonitrile,
- Biomass recycling,
- CEI analysis,
- Na-Se batteries
1. [1]
  J.K. Kim, Y.C. Kang, ACS Nano 14 (2020) 13203–13216. doi: 10.1021/acsnano.0c04870
2. [2]
  W.D. Dong, Y. Li, C.F. Li, et al., Nano Energy 105 (2023) 108005. doi: 10.1016/j.nanoen.2022.108005
3. [3]
  F. Zhang, B. He, Y. Xin, et al., Chem. Rev. 124 (2024) 4778–4821. doi: 10.1021/acs.chemrev.3c00728
4. [4]
  H. Wang, H. Chen, C. Chen, et al., Chin. Chem. Lett. 34 (2023) 107465. doi: 10.1016/j.cclet.2022.04.063
5. [5]
  Y. Su, S. Liu, D. Zhu, et al., Energy Storage Mater. 59 (2023) 102779. doi: 10.1016/j.ensm.2023.102779
6. [6]
  K. Du, R. Tao, C. Guo, et al., Nano Energy 103 (2022) 107862. doi: 10.1016/j.nanoen.2022.107862
7. [7]
  S. Wei, H. Chen, F. Yu, et al., J. Power Sources 598 (2024) 234193. doi: 10.1016/j.jpowsour.2024.234193
8. [8]
  L. Liu, R. Zhang, S. Li, et al., Electrochim. Acta 479 (2024) 143907. doi: 10.1016/j.electacta.2024.143907
9. [9]
  G. Wang, Y. Chen, Y. Han, et al., J. Energy Chem. 80 (2023) 99–109. doi: 10.1016/j.jechem.2022.12.054
10. [10]
  H. Chen, C. Zhao, H. Yue, et al., Chin. Chem. Lett. 36 (2025) 109650. doi: 10.1016/j.cclet.2024.109650
11. [11]
  Q. Xia, J. Hu, Q. Chen, et al., J. Alloy. Compd. 927 (2022) 167014. doi: 10.1016/j.jallcom.2022.167014
12. [12]
  Q. Xia, Y. Zou, K. Yan, et al., J. Colloid Interf. Sci. 667 (2024) 282–290. doi: 10.1016/j.jcis.2024.04.083
13. [13]
  M.H.A. Shiraz, P. Zhao, J. Liu, J. Power Sources 453 (2020) 227855. doi: 10.1016/j.jpowsour.2020.227855
14. [14]
  X.L. Huang, C. Zhou, W. He, et al., ACS Nano 15 (2021) 5876–5903. doi: 10.1021/acsnano.0c10078
15. [15]
  Q. Xia, J. Hu, Q. Chen, et al., J. Colloid Interf. Sci. 610 (2022) 643–652. doi: 10.1016/j.jcis.2021.11.106
16. [16]
  M. Asif, Z. Ali, M. Ali, et al., J. Colloid Interf. Sci. 617 (2022) 641–650. doi: 10.1016/j.jcis.2022.03.024
17. [17]
  X. Qi, Y. Yang, Q. Jin, et al., Angew. Chem. Int. Ed. 59 (2020) 13908–13914. doi: 10.1002/anie.202004424
18. [18]
  H. Wang, Y. Jiang, A. Manthiram, Adv. Energy Mater. 8 (2017) 13908–13914.
19. [19]
  H. Tian, H. Tian, S. Wang, et al., Nat. Commun. 11 (2020) 5025. doi: 10.1038/s41467-020-18820-y
20. [20]
  W.D. Dong, W.B. Yu, F.J. Xia, et al., J. Colloid Interf. Sci. 582 (2021) 60–69. doi: 10.1016/j.jcis.2020.06.071
21. [21]
  Y. Zhang, J. Wang, Z. Xue, Adv. Funct. Mater. 34 (2023) 2311925.
22. [22]
  D. Ma, Y. Li, J. Yang, et al., Nano Energy 43 (2018) 317–325. doi: 10.1016/j.nanoen.2017.11.042
23. [23]
  M. Zhou, W. Dong, A. Xu, et al., Chem. Eng. J. 455 (2023) 140803. doi: 10.1016/j.cej.2022.140803
24. [24]
  W.D. Dong, C.F. Li, H.Y. Li, et al., J. Mater. Chem. A 10 (2022) 8059–8067. doi: 10.1039/d1ta10193e
25. [25]
  A. Xu, Q. Xia, S. Zhang, et al., Small 15 (2019) 1903521. doi: 10.1002/smll.201903521
26. [26]
  Q. Xia, A. Xu, L. Du, et al., J. Alloy. Compd. 800 (2019) 50–57. doi: 10.1016/j.jallcom.2019.06.023
27. [27]
  J. Hu, Q. Chen, Q. Xia, et al., Appl. Surf. Sci. 599 (2022) 153951. doi: 10.1016/j.apsusc.2022.153951
28. [28]
  Y. Su, S. Liu, D. Zhu, et al., Energy Storage Mater. 59 (2023) 102779. doi: 10.1016/j.ensm.2023.102779
29. [29]
  D.M. Piper, T.A. Yersak, S.B. Son, et al., Adv. Energy Mater. 3 (2013) 697–702. doi: 10.1002/aenm.201200850
30. [30]
  J. Hu, L. Zhang, J. Mater. Chem. A 9 (2021) 27560–27567. doi: 10.1039/d1ta07749j
31. [31]
  Z. Song, G. Wang, Y. Chen, et al., Chem. Eng. J. 463 (2023) 142289. doi: 10.1016/j.cej.2023.142289
32. [32]
  X.L. Huang, X. Zhang, M. Yi, et al., Chem. Sci. 13 (2022) 11585–11593. doi: 10.1039/d2sc04648b
33. [33]
  Q. Hu, J. Lu, C. Yang, et al., Small 16 (2020) 2002046. doi: 10.1002/smll.202002046
34. [34]
  Y. Lu, C.Z. Zhao, J.Q. Huang, et al., Joule 6 (2022) 1172–1198. doi: 10.1016/j.joule.2022.05.005
35. [35]
  R. Soni, J.B. Robinson, P.R. Shearing, et al., Energy Storage Mater. 51 (2022) 97–107. doi: 10.1016/j.ensm.2022.06.016
36. [36]
  Y. Sun, J. Liao, J. Sun, et al., ACS Appl. Energy Mater. 5 (2022) 13023–13030. doi: 10.1021/acsaem.2c02679
37. [37]
  Q. Xia, A. Xu, C. Huang, et al., ChemElectroChem 6 (2019) 4402–4410. doi: 10.1002/celc.201901111
38. [38]
  S. Vallem, S. Song, Y. Oh, et al., Small Methods 8 (2024) 2400294. doi: 10.1002/smtd.202400294
39. [39]
  Y. Tong, Y. Wu, Z. Liu, et al., Chin. Chem. Lett., 34 (2023) 107443. doi: 10.1016/j.cclet.2022.04.041
40. [40]
  S. Li, J. Zhu, W. Lu, et al., J. Colloid. Interf. Sci. 663 (2024) 801–809. doi: 10.1016/j.jcis.2024.03.004
41. [41]
  Z. Song, G. Wang, Y. Chen, et al., Chem. Eng. J. 435 (2022) 134633. doi: 10.1016/j.cej.2022.134633
42. [42]
  J. Li, J. Song, L. Luo, et al., Adv. Energy Mater. 12 (2022) 2200894. doi: 10.1002/aenm.202200894
43. [43]
  A. Darwiche, L. Bodenes, L. Madec, et al., Electrochim. Acta 207 (2016) 284–292. doi: 10.1016/j.electacta.2016.03.089
44. [44]
  X. Gao, X. Dong, Z. Xing, et al., Nanoscale 15 (2023) 1568–1582. doi: 10.1039/d2nr05885e
45. [45]
  G.G. Eshetu, T. Diemant, M. Hekmatfar, et al., Nano Energy 55 (2019) 327–340. doi: 10.1016/j.nanoen.2018.10.040
46. [46]
  W.E. Morgan, J.R. Van Wazer, W.J. Stec, J. Am. Chem. Soc. 95 (1973) 751–755. doi: 10.1021/ja00784a018
47. [47]
  S. Wang, C. Li, X. Fan, et al., Energy Technol. 9 (2021) 2100190. doi: 10.1002/ente.202100190
48. [48]
  R. Xu, Q. Liu, Q. Yang, et al., Electrochim. Acta 462 (2023) 142787. doi: 10.1016/j.electacta.2023.142787
49. [49]
  Q. Zhang, J. Ma, L. Mei, et al., Matter 5 (2022) 1235–1250. doi: 10.1016/j.matt.2022.01.015
50. [50]
  X. Zuo, C. Fan, X. Xiao, et al., J. Power Sources 219 (2012) 94–99. doi: 10.1016/j.jpowsour.2012.07.026
51. [51]
  Q. He, H. Chen, X. Chen, et al., Adv. Funct. Mater. 34 (2024) 2310226. doi: 10.1002/adfm.202310226
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