Citation: Qianxi Wang, Xiaoqi Li, Fen Zhang, Qingyin Wei, Zengshan Yue, Xiantan Lin, Yicong Lv, Xitao Liu, Junhua Luo. Mixed cation ordering scaffold polar 2D halide perovskite semiconductor for self-powered polarization-sensitive photodetection[J]. Chinese Chemical Letters, ;2025, 36(10): 110405. doi: 10.1016/j.cclet.2024.110405 shu

Mixed cation ordering scaffold polar 2D halide perovskite semiconductor for self-powered polarization-sensitive photodetection

Qianxi Wang ^{a, b} ,
Xiaoqi Li ^{b, c} ,
Fen Zhang ^b ,
Qingyin Wei ^{a, b} ,
Zengshan Yue ^{a, b} ,
Xiantan Lin ^b ,
Yicong Lv ^b ,
Xitao Liu ^{a, b, c, *,} ,
Junhua Luo ^{a, b, c, *,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350116, China
b.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

xtliu@fjirsm.ac.cn

jhluo@fjirsm.ac.cn

Received Date: 20 June 2024
Revised Date: 9 August 2024
Accepted Date: 3 September 2024
Available Online: 14 September 2024

Figures(5)

Polar semiconductors, particularly the emerging polar two-dimensional (2D) halide perovskites, have motivated immense interest in diverse photoelectronic devices due to their distinguishing polarization-generated photoelectric effects. However, the constraints on the organic cation's choice are still subject to limitations of polar 2D halide perovskites due to the size of the inorganic pocket between adjacent corner-sharing octahedra. Herein, a mixed spacer cation ordering strategy is employed to assemble a polar 2D halide perovskite NMAMAPbBr₄ (NMPB, NMA is N-methylbenzene ammonium, MA is methylammonium) with alternating cation in the interlayer space. Driven by the incorporation of a second MA cation, the perovskite layer transformed from a 2D Pb₇Br₂₄ anionic network with corner- and face-sharing octahedra to a flat 2D PbBr₄ perovskite networks only with corner-sharing octahedra. In the crystal structure of NMPB, the asymmetric hydrogen-bonding interactions between ordered mixed-spacer cations and 2D perovskite layers give rise to a second harmonic generation response and a large polarization of 1.3 µC/cm². More intriguingly, the ordered 2D perovskite networks endow NMPB with excellent self-powered polarization-sensitive detection performance, showing a considerable polarization-related dichroism ratio up to 1.87. The reconstruction of an inorganic framework within a crystal through mixed cation ordering offers a new synthetic tool for templating perovskite lattices with controlled properties, overcoming limitations of conventional cation choice.
- Polar semiconductor,
- 2D halide perovskite,
- Mixed cation ordering,
- Self-powered polarization sensitive photodetection,
- ACI-type,
- Bulk photovoltaic effect
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