Citation: Ran Gao, Qian Zou, Qian-Qian Su, Xiu-Fang Ma, Ye-Hui Qin, Rui Liao, Song-Song Bao, Li-Min Zheng. Photoresponsive lanthanide-dianthracene framework: Introduction of photoactive anthracene pairs by controlling the synthesis temperature[J]. Chinese Chemical Letters, ;2025, 36(10): 110404. doi: 10.1016/j.cclet.2024.110404 shu

Photoresponsive lanthanide-dianthracene framework: Introduction of photoactive anthracene pairs by controlling the synthesis temperature

Ran Gao ^a ,
Qian Zou ^{a, b} ,
Qian-Qian Su ^a ,
Xiu-Fang Ma ^a ,
Ye-Hui Qin ^a ,
Rui Liao ^a ,
Song-Song Bao ^{a, *,} ,
Li-Min Zheng ^{a, *,}

a.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
b.
Drilling and Production Technology Research Institute, Chuanqing Drilling Engineering Company Limited, China National Petroleum Corporation, Xi'an 710018, China

baososo@nju.edu.cn

lmzheng@nju.edu.cn

Received Date: 17 July 2024
Revised Date: 11 August 2024
Accepted Date: 3 September 2024
Available Online: 3 September 2024

Figures(5)

Metal-organic frameworks (MOFs) containing face-to-face π-π interacting anthracene groups are promising photoresponsive materials because of their rich photophysical properties and their ability to undergo reversible [4 + 4] photocycloaddition reaction, but it is extremely challenging to obtain such materials. Herein, we propose a generalized method to accomplish photoresponsive MOFs by introducing anthracene pairs into the framework of the dianthracene-phosphonate-based MOFs by controlling the synthesis temperature. Compounds Dy₂(ampH)_2x(amp₂H₂)_3-x(H₂O)₆·4H₂O [x = 0.01, Dy-70; x = 0.02, Dy-80; x = 0.037, Dy-90; amp₂H₄ = pre-photodimerized 9-anthracenemethylphosphonic acid (ampH₂)] were obtained by the reaction of DyCl₃ and amp₂H₄ in water at 70, 80, and 90 ℃, respectively. They all show excimer emission of paired anthracenes at ca. 555 nm. Detailed studies of Dy-90 have shown that it undergoes a reversible photodimerization reaction under 365 nm and then 280 nm illumination, accompanied by luminescence changes. This property further enables Dy-90 to be used for optical anti-counterfeiting.
- Metal-organic framework,
- Photoresponsive,
- Anthracene excimer,
- Phosphonate,
- Anti-counterfeiting
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