Citation: Xin Meng, Xin-Ya Cai, Qing-Rong Ding, Shan-Shan Chen, Shu-Mei Chen, Yan-Ping He, Jian Zhang. Modifying π-conjugated coordination silver cation onto homochiral zirconium-organic cage for circularly polarized luminescence[J]. Chinese Chemical Letters, ;2025, 36(10): 110402. doi: 10.1016/j.cclet.2024.110402 shu

Modifying π-conjugated coordination silver cation onto homochiral zirconium-organic cage for circularly polarized luminescence

Xin Meng ^{a, b} ,
Xin-Ya Cai ^{a, b} ,
Qing-Rong Ding ^b ,
Shan-Shan Chen ^b ,
Shu-Mei Chen ^{a, *,} ,
Yan-Ping He ^{b, *,} ,
Jian Zhang ^b

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

csm@fzu.edu.cn

hyp041@163.com

Received Date: 24 June 2024
Revised Date: 27 August 2024
Accepted Date: 3 September 2024
Available Online: 3 September 2024

Figures(3)

Although many racemic M₄L₆ cages have been synthesized, little attention has been paid to the resolution of M₄L₆ cages because resolution of these cages is very difficult. To explore the use of optically pure M₄L₆ cages in chiral applications, it is important to obtain a single enantiomer. In this work, the anionic ΔΔΔΔ-Zr₄L₆ and ΛΛΛΛ-Zr₄L₆ (L = embonate) cages have been completely separated by introducing chiral organic ligands R/S-BINAP and 1S,2S/1R,2R-DPEN, respectively, and the active vertex of homochiral Zr₄L₆ cage traps π-conjugated coordination silver cations (such as [Ag₂(DPPM)₂]²⁺, chiral [Ag₂(PPh₃)₂(DPEN)]²⁺ and [Ag(PPh₃)(DPEN)]⁺), obtaining two pair of pure enantiomers (PTC-375(Δ/Λ) and PTC-376(Δ/Λ)). Interestingly, the chiral resolution and surface modification of such zirconium cage endow it with homochirality and significant circularly polarized luminescence (CPL) response, and PTC-376 enantiomers show a CPL output with g_lum values up to ~1.4 × 10⁻². This work not only provides a new resolution strategy for metal-organic cages, but also expands their chiral application especially in CPL field.
- Zirconium-organic cage,
- Chiral resolution,
- Post-synthetic modification,
- Structures,
- Circularly polarized luminescence
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