Citation: Wenya Li, Yuanqi Yang, Yuqing Yang, Min Liang, Huizi Li, Xi Ke, Liying Liu, Yan Sun, Chunsheng Li, Zhicong Shi, Su Ma. Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO₂ cathode material for sodium-ion batteries[J]. Chinese Chemical Letters, ;2025, 36(10): 110388. doi: 10.1016/j.cclet.2024.110388 shu

Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO₂ cathode material for sodium-ion batteries

Wenya Li ^a ,
Yuanqi Yang ^a ,
Yuqing Yang ^b ,
Min Liang ^a ,
Huizi Li ^a ,
Xi Ke ^a ,
Liying Liu ^{a, *,} ,
Yan Sun ^{b, *,} ,
Chunsheng Li ^b ,
Zhicong Shi ^a ,
Su Ma ^{b, *,}

a.
School of Materials and Energy, Guangzhou Key Laboratory of Low-dimensional Materials and Energy Storage Devices, Guangdong University of Technology, Guangzhou 510006, China
b.
Key Laboratory of Advanced Electrode Materials for Novel Solar Cells for Petroleum and Chemical Industry of China, School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China

liyingliusy@gdut.edu.cn

juzi147@163.com

masu115@hotmail.com

Received Date: 28 June 2024
Revised Date: 24 July 2024
Accepted Date: 29 August 2024
Available Online: 30 August 2024

Figures(4)

The development of high-performance cathode materials is critical to the practical application of sodium-ion batteries (SIBs). O3-type NaCrO₂ (NCO) is one of the most competitive cathodes, but it suffers from rapid capacity decay caused by severe irreversible structural evolution. An Mg-Ti co-doped Na_0.99Cr_0.95Mg_0.02Ti_0.03O₂ (NCO-MT) cathode material is designed and synthesized via a facile solid-state reaction to enhance the cyclability of NCO. A capacity retention of 71.6% after 2500 cycles with the capacity fade rate of 0.011% per cycle is achieved for NCO-MT at 5 C, which is attributed to the highly reversible crystal structure during cycling. Our findings offer a novel insight into the high-performance O3-type layered cathode materials for SIBs and are beneficial to promote the development of high-rate SIBs.
- Sodium-ion batteries,
- O3-type NaCrO₂,
- Mg-Ti co-doping,
- Cycling stability,
- Structural reversibility
1. [1]
  D. Zhang, L. Li, W. Zhang, et al., Chin. Chem. Lett. 34 (2023) 107122. doi: 10.1016/j.cclet.2022.01.015
2. [2]
  A. Huang, Y. Ma, J. Peng, et al., eScience 1 (2021) 141–162. doi: 10.1016/j.esci.2021.11.006
3. [3]
  J.M. Tarascon, Nat. Chem. 2 (2010) 510. doi: 10.1038/nchem.680
4. [4]
  Q. Liu, Z. Hu, W. Li, et al., Energy Environ. Sci. 14 (2021) 158–179. doi: 10.1039/d0ee02997a
5. [5]
  X. Jin, Y. Huang, M. Zhang, et al., Battery Energy 2 (2023) 20230029. doi: 10.1002/bte2.20230029
6. [6]
  K. Wang, Z. Zhang, S. Cheng, et al., eScience 2 (2022) 529–536. doi: 10.1016/j.esci.2022.08.003
7. [7]
  R. Chen, D.S. Butenko, S. Li, et al., Chin. Chem. Lett. 35 (2024) 108358. doi: 10.1016/j.cclet.2023.108358
8. [8]
  Y. You, S. Xin, H.Y. Asl, et al., Chem 4 (2018) 2124–2139. doi: 10.1016/j.chempr.2018.05.018
9. [9]
  M. Guignard, C. Didier, J. Darriet, et al., Nat. Mater. 12 (2013) 74–80. doi: 10.1038/nmat3478
10. [10]
  J. Zhao, L. Zhao, K. Chihara, et al., J. Power Sources 244 (2013) 752–757. doi: 10.1016/j.jpowsour.2013.06.109
11. [11]
  S. Komab, C. Takei, T. Nakayama, et al., Electrochem. Commun. 12 (2010) 355–358. doi: 10.1016/j.elecom.2009.12.033
12. [12]
  E. Lee, J. Lu, Y. Ren, et al., Adv. Energy Mater. 4 (2014) 1400458. doi: 10.1002/aenm.201400458
13. [13]
  J. Qian, M. Zhou, Y. Cao, et al., Adv. Energy Mater. 2 (2012) 410–414. doi: 10.1002/aenm.201100655
14. [14]
  L. Xu, H. Li, T. Du, et al., Battery Energy 1 (2022) 20210003. doi: 10.1002/bte2.20210003
15. [15]
  K. Hurlbutt, S. Wheeler, I. Capone, et al., Joule 2 (2018) 1950–1960.
16. [16]
  B. Wang, Y. Han, X. Wang, et al., iScience 3 (2018) 110–133. doi: 10.1016/j.isci.2018.04.008
17. [17]
  Q. Ni, Y. Bai, F. Wu, et al., Adv. Sci. 4 (2017) 1600275.
18. [18]
  Z. Jian, X. Lu, H. Yang, et al., Adv. Energy Mater. 3 (2013) 156–160. doi: 10.1002/aenm.201200558
19. [19]
  K. Saravanan, C.W. Mason, A. Rudola, et al., Adv. Energy Mater. 3 (2013) 444–450. doi: 10.1002/aenm.201200803
20. [20]
  W. Li, J. Li, R. Li, et al., Battery Energy 2 (2023) 20220042.
21. [21]
  K. Liang, D. Wu, Y. Ren, et al., Chin. Chem. Lett. 34 (2023) 107978. doi: 10.1016/j.cclet.2022.107978
22. [22]
  C. Delmas, C. Fouassier, P. Hagenmuller, Phys. B+C 99 (1980) 81–85.
23. [23]
  J.J. Braconnier, C. Delmas, C. Fouassier, et al., Mater. Res. Bull. 15 (1980) 1797–1804. doi: 10.1016/0025-5408(80)90199-3
24. [24]
  K. Kubota, I. Ikeuchi, T. Nakayama, et al., J. Phys. Chem. C 119 (2014) 166–175.
25. [25]
  C. Yu, J.S. Park, H.G. Jung, et al., Energy Environ. Sci. 8 (2015) 2019–2026.
26. [26]
  W. Li, Y. Wang, G. Hu, et al., J. Alloy. Compd. 779 (2019) 147–155.
27. [27]
  S. Wang, F. Chen, T. Zhu, et al., ACS Appl. Mater. Interfaces 12 (2020) 44671–44678. doi: 10.1021/acsami.0c11320
28. [28]
  C. Ma, X. Li, X. Yue, et al., Chem. Eng. J. 432 (2022) 134305.
29. [29]
  W. Li, M. Liang, Y. Yang, et al., Mater. Lett. 352 (2023) 135141.
30. [30]
  L. Liang, W. Zhang, D.K. Denis, J. Mater. Chem. A 7 (2019) 11915–11927. doi: 10.1039/c9ta01540j
31. [31]
  L. Liang, X. Sun, D.K. Denis, et al., ACS Appl. Mater. Interfaces 11 (2019) 4037–4046. doi: 10.1021/acsami.8b20149
32. [32]
  T. Hwang, J.H. Lee, S.H. Choi, et al., ACS Appl. Mater. Interfaces 11 (2019) 30894–30901. doi: 10.1021/acsami.9b08987
33. [33]
  H. Hou, J. Qiu, B. Li, et al., Chin. Chem. Lett. 34 (2023) 108810.
34. [34]
  J. Feng, J. Wang, P. Li, et al., ACS Sustain. Chem. Eng. 10 (2022) 4994–5004. doi: 10.1021/acssuschemeng.2c00197
35. [35]
  J. Billaud, G. Singh, A.R. Armstrong, et al., Energy Environ. Sci. 7 (2014) 1387–1391.
36. [36]
  Y. Wang, R. Xiao, Y. Hu, et al., Nat. Commun. 6 (2015) 6954.
37. [37]
  I. Lee, G. Oh, S. Lee, et al., Energy Storage Mater. 41 (2021) 183–195.
38. [38]
  Y. Hu, Y. Lu, ACS Energy Lett. 4 (2019) 2689–2690. doi: 10.1021/acsenergylett.9b02190
39. [39]
  Y. Tsuchiya, K. Takaanashi, T. Nishinobo, et al., Chem. Mater. 28 (2016) 7006–7016. doi: 10.1021/acs.chemmater.6b02814
40. [40]
  J. Ding, Y. Zhou, Q. Sun, et al., Electrochem. Commun. 22 (2012) 85–88.
41. [41]
  J. Liang, L. Liu, X. Liu, et al., ACS Appl. Mater. Interfaces 13 (2021) 22635–22645. doi: 10.1021/acsami.1c04997
42. [42]
  Q. Liu, Z. Hu, M. Chen, et al., Small 15 (2019) e1805381.
43. [43]
  Y. Wang, P. Cui, W. Zhu, et al., J. Power Sources 435 (2019) 226760.
44. [44]
  C. Lin, X. Meng, M. Liang, et al., J. Mater. Chem. A 11 (2023) 68–76. doi: 10.1039/d2ta07413c
45. [45]
  R.J. Clément, J. Billaud, A.R. Armstrong, et al., Energy Environ. Sci. 9 (2016) 3240–3251.
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6. [6]
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18. [18]
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19. [19]
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO2 cathode material for sodium-ion batteries

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通讯作者: 陈斌, bchen63@163.com

Insights into magnesium and titanium co-doping to stabilize the O3-type NaCrO₂ cathode material for sodium-ion batteries