Citation: Li-Min Cui, Wei-Hui Fang, Jian Zhang. Polyoxometalates containing aluminum atoms[J]. Chinese Chemical Letters, ;2025, 36(10): 110386. doi: 10.1016/j.cclet.2024.110386 shu

Polyoxometalates containing aluminum atoms

Li-Min Cui ^{a, b} ,
Wei-Hui Fang ^{a, *,} ,
Jian Zhang ^a

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

fwh@fjirsm.ac.cn

Received Date: 20 June 2024
Revised Date: 2 August 2024
Accepted Date: 29 August 2024
Available Online: 30 August 2024

Figures(6)

For a long time, researchers have been fascinated by the structurally diverse and high-performance characteristics of polyoxometalates (POMs). Modifying POMs with various types and properties of metals has broadened their applications in fields such as magnetism, luminescence, and catalysis. However, despite the discovery of numerous POM structures doped with transition metal ions, the development of aluminum (Al) as a ⅢA group metal in the POM field has been slow. Aluminum, the most abundant metal in nature, offers innate electron-deficient properties that, when combined with highly charged POMs, could introduce novel structures and excellent functionalities like proton conduction to this field. Therefore, this review will address the gap in summarizing Al-containing POMs by categorizing and summarizing the synthesis, structural characteristics, and properties of Al-containing POMs, aiming to provide a theoretical foundation for exploring POM structures doped with Al atoms. The review also analyzes and forecasts the prospects in this field.
- Polyoxometalate,
- Aluminum,
- Polyoxoaluminate,
- Ionic crystal,
- Catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142