Citation: Zhiwei Zhong, Yanbin Huang, Wantai Yang. A simple photochemical method for surface fluorination using perfluoroketones[J]. Chinese Chemical Letters, ;2024, 35(5): 109339. doi: 10.1016/j.cclet.2023.109339 shu

A simple photochemical method for surface fluorination using perfluoroketones

Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

yanbin@tsinghua.edu.cn

yangwantai@tsinghua.edu.cn

Received Date: 28 August 2023
Revised Date: 19 November 2023
Accepted Date: 23 November 2023
Available Online: 25 November 2023

Figures(6)

Surface fluorination of conventional polymers can give them desirable surface properties similar to the expensive and difficult-to-process fluoropolymers. However, traditional surface fluorination techniques often require toxic reagents and special equipment. Here, we report a simple and effective polymer surface fluorination method by using safe and inexpensive perfluoro-2-methyl-3-pentanone (PFMP, C₂F₅C(O)CF(CF₃)₂) and UV irradiation. This method is applicable to various polymer materials, and generates nanometer-thick fluorinated layer on the outermost surface, significantly changing their surface properties without changing the surface morphology.
- Surface fluorination,
- Perfluoroketone,
- UV irradiation,
- Photochemistry,
- Surface free energy
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