Citation: Dai-Huo Liu, Ao Wang, Hong-Yan Lü, Xing-Long Wu, Dan Luo, Wen-Hao Li, Jin-Zhi Guo, Haozhen Dou, Qianyi Ma, Zhongwei Chen. In situ constructing (MnS/Mn₂SnS₄)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells[J]. Chinese Chemical Letters, ;2024, 35(11): 109285. doi: 10.1016/j.cclet.2023.109285 shu

In situ constructing (MnS/Mn₂SnS₄)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells

Dai-Huo Liu ^{a, d} ,
Ao Wang ^{a, d} ,
Hong-Yan Lü ^{b, *,} ,
Xing-Long Wu ^{b, c} ,
Dan Luo ^d ,
Wen-Hao Li ^b ,
Jin-Zhi Guo ^c ,
Haozhen Dou ^d ,
Qianyi Ma ^e ,
Zhongwei Chen ^{d, e, *,}

a.
Key Laboratory of Green Chemical Media and Reaction, Ministry of Education, Collaborative Innovation Center of Henan Province for Fine Chemicals Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China
b.
Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
c.
MOE Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Changchun 130024, China
d.
Power Battery and Systems Research Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
e.
Department of Chemical Engineering, Waterloo Institute for Nanotechnology, Waterloo Institute for Sustainable Energy, Waterloo University, Waterloo, ON N2L 3G1, Canada

luhy836@nenu.edu.cn

zhwchen@uwaterloo.ca

Received Date: 18 August 2023
Revised Date: 26 September 2023
Accepted Date: 6 November 2023
Available Online: 8 November 2023

Figures(6)

Effective design of nanoheterostructure anode with high ion/electron migration kinetics can give electrode with superior electrochemical performance. However, the design and preparation of nanoheterostructure composites with high-capacity and long cycling life in half and pouch full cells remain a big challenge. Here, a novel micro-pore MnS/Mn₂SnS₄ heterostructure nanowire were in situ encapsulated into the N and S elements co-doped amorphous carbon tubes (abbreviated as (MnS/Mn₂SnS₄)@N,S-ACTs) and showed superior energy storage properties in Na-/Li-ion half cells and pouch full cells. The Na-/Li-storage capabilities improvement are attribute to the strong synergistic effect between MnS/Mn₂SnS₄ heterostructure and N,S-ACTs protective layer, the former induces an local built-in electric field between Mn₂SnS₄ and MnS during charging/discharging, accelerating interfacial ion/electron diffusion dynamics, the latter effective maintains the morphology and volume evolution during Na⁺/Li⁺ charging/discharging, achieving a long-term cycling stability (e.g., high discharge capacity of 79.2 mAh/g with the capacity retention of 79.3% can be gained after 2200 cycles at 3 C in (MnS/Mn₂SnS₄)@N,S-ACTs//LiFePO₄ pouch full cells; a high capacity of ~34 mAh/g at 10 C can be got with a Coulombic efficiency of 100% after 1000 cycles in pouch (MnS/Mn₂SnS₄)@N,S-ACTs//Na₃V₂(PO₄)₂O₂F full cells.
- (MnS/Mn₂SnS₄)@N,S-ACTs,
- Heterostructure,
- Long cycling life,
- Na-/Li-ion half cells,
- Pouch full cells
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沈阳化工大学材料科学与工程学院沈阳 110142

In situ constructing (MnS/Mn2SnS4)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells

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通讯作者: 陈斌, bchen63@163.com

In situ constructing (MnS/Mn₂SnS₄)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells