Citation: Ting-Ting Huang, Jin-Fa Chen, Juan Liu, Tai-Bao Wei, Hong Yao, Bingbing Shi, Qi Lin. A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect[J]. Chinese Chemical Letters, ;2024, 35(7): 109281. doi: 10.1016/j.cclet.2023.109281 shu

A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect

Ting-Ting Huang ^a ,
Jin-Fa Chen ^a ,
Juan Liu ^b ,
Tai-Bao Wei ^a ,
Hong Yao ^a ,
Bingbing Shi ^a ,
Qi Lin ^{a, *,}

a.
Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Key Laboratory of Eco-environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
b.
Key Laboratory of Environment-Friendly Composite Materials of the State Ethnic Affairs Commission, Gansu Provincial Biomass Function Composites Engineering Research Center, College of Chemical Engineering, Northwest Minzu University (Northwest University for Nationalities), Lanzhou 730000, China

linqi2004@126.com

Received Date: 4 August 2023
Revised Date: 27 October 2023
Accepted Date: 6 November 2023
Available Online: 9 November 2023

Figures(5)

Improving the highly selective and sensitive binding of chemosensor to target guest is always very challenging. In order to solve this issue, herein, the enrichment effect was introduced into the design of chemosensor molecule. A novel bi-fused-macrocyclic host molecule BPN1 was synthesized by bridging a pillar[5]arene and a naphthalene diimide (NDI) group through hydrogen-bond-rich chain. In the BPN1, the naphthalimide side ring is outside the cavity of the pillar[5]arene. In addition, Cr(Ⅵ) greatly threat human health and the environment due to its severe toxicity, and it is very important to develop effective chemosensor for sensitive and selective detection of Cr₂O₇²⁻ or its ion pairs. In this paper, the novel bi-fused-macrocyclic host molecule BPN1 can recognize Cr₂O₇²⁻ with high selectivity and sensitivity. The mechanism of BPN1 recognition of Cr₂O₇²⁻ was studied through experiments and density functional theory (DFT), the results show that BPN1 could supply enrichment effect to bind Cr₂O₇²⁻ through multiple weak interactions such as hydrogen bonds and anion-π, and achieve highly sensitive and selective detection of Cr₂O₇²⁻. It is a significant and feasible strategy for improve high selectivity and sensitivity of host to specific objects by using the enrichment effect of fused bi-macrocyclic.
- Pillar[5]arene,
- Bi-macrocyclic,
- Detection of Cr₂O₇²⁻,
- DFT,
- The enrichment effect
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A novel fused bi-macrocyclic host for sensitive detection of Cr2O72− based on enrichment effect

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通讯作者: 陈斌, bchen63@163.com

A novel fused bi-macrocyclic host for sensitive detection of Cr₂O₇²⁻ based on enrichment effect