Citation: Haojie Duan, Hejingying Niu, Lina Gan, Xiaodi Duan, Shuo Shi, Li Li. Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂[J]. Chinese Chemical Letters, ;2024, 35(6): 109038. doi: 10.1016/j.cclet.2023.109038 shu

Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂

Haojie Duan ^a ,
Hejingying Niu ^{a, *,} ,
Lina Gan ^{b, *,} ,
Xiaodi Duan ^a ,
Shuo Shi ^c ,
Li Li ^a

a.
School of Environmental & Chemical Engineering, Shanghai University, Shanghai 200444, China
b.
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China
c.
Shanghai Aircraft Design and Research Institute, Shanghai 201210, China

niuhjy@shu.edu.cn

lngan@usst.edu.cn

Received Date: 31 May 2023
Revised Date: 3 August 2023
Accepted Date: 1 September 2023
Available Online: 3 September 2023

Figures(4)

Heterogeneous reaction of mineral aerosols and atmospheric polluting gases play an important role in atmospheric chemistry. In this study, the reactions of NO₂ with or without SO₂ mixture gas on the surface of α-Fe₂O₃ particles under dry conditions were studied. The effects of sodium dodecyl sulfate (SDS) and the heterogeneous reaction under both dark and UV irradiation conditions were investigated. The infrared spectrum analyzed by the two-dimensional correlation spectroscopy (2D-COS) was used to obtain the products formation sequences. The results showed that UV irradiation can promote the production of nitrate. The 2D-COS analysis indicated SDS changed the sequence order of nitrate and nitrite species during reactions. In oxidation conditions, the final product of heterogeneous reaction of NO₂ and α-Fe₂O₃ was monodentate nitrate. Only the heterogenous reaction of NO₂ and α-Fe₂O₃ containing SDS (FOS) without UV light, the final product was bidentate nitrate. SDS was the catalysis agent supply and photoresist to the system. With surface active compounds, the environmental lifetime of heterogeneous reactions between trace gases and aerosols extends. Surfactants, ultraviolet light, and the types of gases involved in the reaction all have complex effects on the aerosol aging process. This study provided a reference for subsequent heterogeneous reaction studies and the formation of aerosols.
- Heterogeneous reaction,
- α-Fe₂O₃,
- 2D-COS,
- SDS,
- Aerosol
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沈阳化工大学材料科学与工程学院沈阳 110142

Reinterpret the heterogeneous reaction of α-Fe2O3 and NO2 with 2D-COS: The role of SDS, UV and SO2

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通讯作者: 陈斌, bchen63@163.com

Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂