Citation: Zhijia Zhang, Shihao Sun, Yuefang Chen, Yanhao Wei, Mengmeng Zhang, Chunsheng Li, Yan Sun, Shaofei Zhang, Yong Jiang. Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage[J]. Chinese Chemical Letters, ;2024, 35(7): 108922. doi: 10.1016/j.cclet.2023.108922 shu

Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage

Zhijia Zhang ^{a, *,} ,
Shihao Sun ^a ,
Yuefang Chen ^a ,
Yanhao Wei ^a ,
Mengmeng Zhang ^a ,
Chunsheng Li ^{b, c, *,} ,
Yan Sun ^{b, c} ,
Shaofei Zhang ^{d, *,} ,
Yong Jiang ^a

a.
School of Materials Science and Engineering, Institute of Quantum Materials and Devices, State Key Laboratory of Separation Membrane and Membrane Processes, Tiangong University, Tianjin 300387, China
b.
School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China
c.
Key Laboratory of Advanced Electrode Materials for Novel Solar Cells for Petroleum and Chemical Industry of China, Suzhou University of Science and Technology, Suzhou 215009, China
d.
Hebei Key Laboratory of Flexible Functional Materials/Hebei Key Laboratory of Material Near-Net Forming Technology, School of Materials Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China

zhangzhijia@tiangong.edu.cn

ichsheng@163.com

zhangshaofei988403@163.com

Received Date: 27 July 2023
Revised Date: 2 August 2023
Accepted Date: 9 August 2023
Available Online: 10 August 2023

Figures(5)

Three-dimentional (3D) transition metal selenides with sufficient channels could produce significant superiority on enhancing reaction kinetics for sodium-ion batteries. However, the thorough exploration of 3D architecture with a facile strategy is still challenging. Here we report that a polycrystalline Cu_2-xSe film was epitaxial grown on (220) facets-exposed Cu by direct selenization of a nanoporous Cu skeleton, which is obtained by dealloying rolled CuMn@Cu alloy foil. Density functional theory calculation result shows strong adsorption energy for Se atoms on Cu (220) planes during selenization reaction, rendering a low energy consumption. By virtue of this core-shell 3D nanoporous architecture to offer abundant active sites and endow fast electron/ion transportation, the nanoporous Cu_2-xSe@Cu-0.15 composite electrode exhibits remarkable sodium-ion storage properties with high reversible capacity of 950.6 µAh/cm² at 50 µA/cm², suprior rate capability of 457.6 µAh/cm² at 500 µA/cm², as well as an ultra-long stability at a high current density. Mechanism investigation reveals that the electrochemical reaction is a typical conversion-type reaction with different intermediates. This novel electrode synthetic strategy provides useful instructions to design the high-performance anode material for sodium-ion batteries.
- Cu2se,
- 3D architecture,
- Anode materials,
- Density functional theory calculation,
- Sodium-ion battery
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Epitaxial growth of Cu2-xSe on Cu (220) crystal plane as high property anode for sodium storage

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通讯作者: 陈斌, bchen63@163.com

Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage