Citation: Xu-Hui Yue, Xiang-Wen Zhang, Hui-Min He, Lei Qiao, Zhong-Ming Sun. Synthesis, chemical bonding and reactivity of new medium-sized polyarsenides[J]. Chinese Chemical Letters, ;2024, 35(7): 108907. doi: 10.1016/j.cclet.2023.108907 shu

Synthesis, chemical bonding and reactivity of new medium-sized polyarsenides

Xu-Hui Yue ^a ,
Xiang-Wen Zhang ^a ,
Hui-Min He ^{b, *,} ,
Lei Qiao ^a ,
Zhong-Ming Sun ^{a, *,}

a.
State Key Laboratory of Element-Organic Chemistry, Tianjin Key Lab for Institution Rare Earth Materials and Applications, School of Materials Science and Engineering, Nankai University, Tianjin 300350, China
b.
Department of Physics, Institute of Computational and Applied Physics, Taiyuan Normal University, Jinzhong 030619, China

hehm@tynu.edu.cn

sunlab@nankai.edu.cn

Received Date: 9 July 2023
Revised Date: 29 July 2023
Accepted Date: 7 August 2023
Available Online: 8 August 2023

Figures(8)

Gaining an understanding of the growth mechanism from single atoms to clusters and bulk materials continues to present a challenge. Thus, it is important to explore the evolving trends of clusters in the structure and properties during the size evolution. In this work, we report the synthesis and characterization of two medium-sized chain-like polyarsenic anions. [As₂₁]^3– represents a trimeric example of polyarsenic anion assembled through oxidative coupling of As₇^3– anions. The anion As₁₈^4– included in [As₁₈Mo₂(CO)₈]^4– is regarded as formed by two realgar-type As₈ subunits connected by a dinuclear As-As dumbbell. The As₁₈ cluster was previously predicted by theory, and this is the first time successfully synthesized using wet chemistry method. Besides, small-sized polyarsenides As₂^2– and As₁₀^2– were found in compound [K(18-crown-6)]₃[As₁₀]_0.5[As₄{Mo(CO)₃}₂]_0.5·2en. Among these, the former exhibits coordination with metal atoms. Single-crystal X-ray diffraction combined with quantum chemical calculations revealed the formation of double bonded As₂^2– stabilized by metal carbonyl groups. This work demonstrates a novel synthetic approach for the preparation of new polyarsenides and highlights their intriguing bonding characteristics, laying the foundation for the synthesis of such compounds and paving the way for their potential applications.
- Polyarsenide,
- Zintl anions,
- Chain-like cluster,
- DFT calculations,
- AdNDP
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