Citation: Xin Dong, Jing Liang, Zhijin Xu, Huajie Wu, Lei Wang, Shihai You, Junhua Luo, Lina Li. Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection[J]. Chinese Chemical Letters, ;2024, 35(6): 108708. doi: 10.1016/j.cclet.2023.108708 shu

Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection

Xin Dong ^{a, b} ,
Jing Liang ^{a, b} ,
Zhijin Xu ^b ,
Huajie Wu ^b ,
Lei Wang ^b ,
Shihai You ^{b, c} ,
Junhua Luo ^{b, c, *,} ,
Lina Li ^{b, c, *,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350116, China
b.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

jhluo@fjirsm.ac.cn

lilina@fjirsm.ac.cn

Received Date: 18 May 2023
Revised Date: 15 June 2023
Accepted Date: 19 June 2023
Available Online: 24 June 2023

Figures(4)

Lead-halide perovskites exhibit outstanding performance in X-ray detection due to their intrinsic features such as high charge carrier mobility, large atomic number, and long carrier lifetime, but the toxicity of lead is regarded as the major factor hindering their development. Here, we introduce organic molecule (R)-(-)-2-methylpiperazine (R-MPz) into the bismuth-based structure to synthesize lead-free (R)-(H₂MPz)BiI₅ (R-MBI). The high-quality centimeter-sized single crystals have been obtained, which show a low dark current and superior environmental stability. Particularly, the single-crystal device of R-MBI exhibits a high μτ product up to 1.88 × 10⁻⁴ cm²/V and a low trap density of 1.21 × 10¹⁰ cm⁻³. Further, the detector displays excellent detection sensitivity of 263.58 µC Gy_air⁻¹ cm⁻² and a favorable low detection limit of 4.35 µGy_air/s, both of which meet the requirement for medical diagnostics. These findings shed light on the exploration of innovative bismuth-based hybrid perovskites for high-performance X-ray detection.
- Perovskite,
- Lead-free,
- Bismuth-based,
- X-ray detection,
- Sensitivity
1. [1]
  Y. He, C.C. Stoumpos, I. Hadar, et al., J. Am. Chem. Soc. 143 (2021) 2068–2077. doi: 10.1021/jacs.0c12254
2. [2]
  H. Wei, Y. Fang, P. Mulligan, et al., Nat. Photonics 10 (2016) 333–339. doi: 10.1038/nphoton.2016.41
3. [3]
  J. Liu, B. Shabbir, C. Wang, et al., Adv. Mater. 31 (2019) 1901644. doi: 10.1002/adma.201901644
4. [4]
  A. Sakdinawat, D. Attwood, Nat. Photonics 4 (2010) 840–848. doi: 10.1038/nphoton.2010.267
5. [5]
  Z. Liu, J.A. Peters, H. Li, et al., J. Electron. Mater. 44 (2015) 222–226. doi: 10.1007/s11664-014-3372-2
6. [6]
  Y. Li, Y. Lei, H. Wang, et al., Nano-Micro Lett. 15 (2023) 128. doi: 10.1007/s40820-023-01118-1
7. [7]
  Z. Xu, X. Liu, Y. Li, et al., Angew. Chem. Int. Ed. 58 (2019) 15757–15761. doi: 10.1002/anie.201909815
8. [8]
  W. Yuan, G. Niu, Y. Xian, et al., Adv. Funct. Mater. 29 (2019) 1900234. doi: 10.1002/adfm.201900234
9. [9]
  S. Kasap, J.B. Frey, G. Belev, et al., Sensors 11 (2011) 5112–5157. doi: 10.3390/s110505112
10. [10]
  Z. Gou, W. Liu, S. Huanglong, et al., IEEE Electron Device Lett. 40 (2019) 578–581. doi: 10.1109/led.2019.2897757
11. [11]
  P. Duvauchelle, G. Peix, D. Babot, Nucl. Instrum. Methods Phys. Res. Sect. B 155 (1999) 221–228. doi: 10.1016/S0168-583X(99)00450-4
12. [12]
  M. Jeong, W.J. Jo, H.S. Kim, et al., Nucl. Instrum. Methods Phys. Res. Sect. A 784 (2015) 119–123. doi: 10.1016/j.nima.2014.11.013
13. [13]
  G. Belev, S.O. Kasap, J. Non-Cryst. Solids 345–346 (2004) 484–488.
14. [14]
  D. Yang, R. Yang, K. Wang, et al., Nat. Commun. 9 (2018) 3239. doi: 10.1038/s41467-018-05760-x
15. [15]
  J.C. Blancon, J. Even, C.C. Stoumpos, et al., Nat. Nanotechnol. 15 (2020) 969–985. doi: 10.1038/s41565-020-00811-1
16. [16]
  H. Wei, D. DeSantis, W. Wei, et al., Nat. Mater. 16 (2017) 826–833. doi: 10.1038/nmat4927
17. [17]
  X. He, Y. Deng, D. Ouyang, et al., Chem. Rev. 123 (2023) 1207–1261. doi: 10.1021/acs.chemrev.2c00404
18. [18]
  L. Li, H. Chen, Z. Fang, et al., Adv. Mater. 32 (2020) 1907257.
19. [19]
  D. Shi, V. Adinolfi, R. Comin, et al., Science 347 (2015) 519–522. doi: 10.1126/science.aaa2725
20. [20]
  Y. He, L. Matei, H.J. Jung, et al., Nat. Commun. 9 (2018) 1609. doi: 10.1038/s41467-018-04073-3
21. [21]
  S. Shrestha, R. Fischer, G.J. Matt, et al., Nat. Photonics 11 (2017) 436–440. doi: 10.1038/nphoton.2017.94
22. [22]
  C. Shan, F. Meng, J. Yu, et al., J. Mater. Chem. C 9 (2021) 7632–7642. doi: 10.1039/d1tc01323h
23. [23]
  W. Xu, M. Niu, X. Yang, et al., Chin. Chem. Lett. 32 (2021) 489–492. doi: 10.1016/j.cclet.2020.05.017
24. [24]
  S. Yakunin, M. Sytnyk, D. Kriegner, et al., Nat. Photonics 9 (2015) 444–449. doi: 10.1038/nphoton.2015.82
25. [25]
  W. Wei, Y. Zhang, Q. Xu, et al., Nat. Photonics 11 (2017) 315–321. doi: 10.1038/nphoton.2017.43
26. [26]
  A. Babayigit, A. Ethirajan, M. Muller, et al., Nat. Mater. 15 (2016) 247–251. doi: 10.1038/nmat4572
27. [27]
  R. Mohan, Nat. Chem. 2 (2010) 336. doi: 10.1038/nchem.609
28. [28]
  R.E. Brandt, R.C. Kurchin, R.L.Z. Hoye, et al., J. Phys. Chem. Lett. 6 (2015) 4297–4302. doi: 10.1021/acs.jpclett.5b02022
29. [29]
  K. Tao, Y. Li, C. Ji, et al., Chem. Mater. 31 (2019) 5927–5932. doi: 10.1021/acs.chemmater.9b02263
30. [30]
  L. Yao, G. Niu, L. Yin, et al., J. Mater. Chem. C 8 (2020) 1239–1243. doi: 10.1039/c9tc06313g
31. [31]
  C. Ji, S. Wang, Y. Wang, et al., Adv. Funct. Mater. 30 (2020) 1905529.
32. [32]
  J.A. Steele, W. Pan, C. Martin, et al., Adv. Mater. 30 (2018) 1804450. doi: 10.1002/adma.201804450
33. [33]
  C. Wang, H. Li, M. Li, et al., Adv. Funct. Mater. 31 (2021) 2009457. doi: 10.1002/adfm.202009457
34. [34]
  W. Pan, H. Wu, J. Luo, et al., Nat. Photonics 11 (2017) 726–732. doi: 10.1038/s41566-017-0012-4
35. [35]
  Q. Cui, X. Song, Y. Liu, et al., Matter 4 (2021) 2490–2507. doi: 10.1016/j.matt.2021.05.018
36. [36]
  J.R. Ayres, J. Appl. Phys. 74 (1993) 1787–1792. doi: 10.1063/1.354782
37. [37]
  A. Balcioglu, R.K. Ahrenkiel, F. Hasoon, J. Appl. Phys. 88 (2000) 7175–7178. doi: 10.1063/1.1326465
38. [38]
  M.J. Berger, J.H. Hubbell, S.M. Seltzer, et al., XCOM: photon Cross Sections Database: NIST Standard Reference Database 8 (NIST), https://www.nist.gov/pml/xcom-photon-cross-sections-database, accessed.
39. [39]
  Y. Liu, H. Ye, Y. Zhang, et al., Matter 1 (2019) 465–480. doi: 10.1016/j.matt.2019.04.002
40. [40]
  J. Androulakis, S.C. Peter, H. Li, et al., Adv. Mater. 23 (2011) 4163–4167. doi: 10.1002/adma.201102450
41. [41]
  Y. Shen, Y. Liu, H. Ye, et al., Angew. Chem. Int. Ed. 59 (2020) 14896–14902. doi: 10.1002/anie.202004160
42. [42]
  Y. Zhang, Y. Liu, Z. Xu, et al., Nat. Commun. 11 (2020) 2304.
43. [43]
  Z. Xu, H. Wu, D. Li, et al., J. Mater. Chem. C 9 (2021) 13157–13161. doi: 10.1039/d1tc03412j
44. [44]
  D.R. Douglas, M. Bopaiah, Health Phys. 79 (2000) S20–S21. doi: 10.1097/00004032-200008001-00007
45. [45]
  I. Clairand, J.M. Bordy, E. Carinou, et al., Radiat. Meas. 46 (2011) 1252–1257.
1. [1]
  Xin Dong , Tianqi Chen , Jing Liang , Lei Wang , Huajie Wu , Zhijin Xu , Junhua Luo , Li-Na Li . Structure design of lead-free chiral-polar perovskites for sensitive self-powered X-ray detection. Chinese Journal of Structural Chemistry, 2024, 43(6): 100256-100256. doi: 10.1016/j.cjsc.2024.100256
2. [2]
  Xiuwen Xu , Quan Zhou , Yacong Wang , Yunjie He , Qiang Wang , Yuan Wang , Bing Chen . Expanding the toolbox of metal-free organic halide perovskite for X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109272-. doi: 10.1016/j.cclet.2023.109272
3. [3]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
4. [4]
  Mohamed Saber Lassoued , Faizan Ahmad , Yanzhen Zheng . Film thickness effect on 2D lead-free hybrid double perovskite properties: Band gap, photocurrent and stability. Chinese Chemical Letters, 2025, 36(4): 110477-. doi: 10.1016/j.cclet.2024.110477
5. [5]
  Xuying Yu , Jiarong Mi , Yulan Han , Cai Sun , Mingsheng Wang , Guocong Guo . A stable radiochromic semiconductive viologen-based metal–organic framework for dual-mode direct X-ray detection. Chinese Chemical Letters, 2024, 35(9): 109233-. doi: 10.1016/j.cclet.2023.109233
6. [6]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
7. [7]
  Ying Wang , Hong Yang , Caixia Zhu , Qing Hong , Xuwen Cao , Kaiyuan Wang , Yuan Xu , Yanfei Shen , Songqin Liu , Yuanjian Zhang . Cascading oxidoreductases-like nanozymes for high selective and sensitive fluorescent detection of ascorbic acid. Chinese Chemical Letters, 2025, 36(4): 110153-. doi: 10.1016/j.cclet.2024.110153
8. [8]
  Botao Gao , He Qi , Hui Liu , Jun Chen . Role of polarization evolution in the hysteresis effect of Pb-based antiferroelecrtics. Chinese Chemical Letters, 2024, 35(4): 108598-. doi: 10.1016/j.cclet.2023.108598
9. [9]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
10. [10]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
11. [11]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
12. [12]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
13. [13]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
14. [14]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
15. [15]
  Xinyu Yu , Fei Wu , Xianglang Sun , Linna Zhu , Baoyu Xia , Zhong'an Li . Low-cost dopant-free fluoranthene-based branched hole transporting materials for efficient and stable n-i-p perovskite solar cells. Chinese Chemical Letters, 2024, 35(10): 109821-. doi: 10.1016/j.cclet.2024.109821
16. [16]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
17. [17]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
18. [18]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
19. [19]
  Dongying Fu , Lin Pan , Yanli Ma , Yue Zhang . Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection. Chinese Chemical Letters, 2025, 36(2): 109621-. doi: 10.1016/j.cclet.2024.109621
20. [20]
  Jingqi Ma , Huangjie Lu , Junpu Yang , Liangwei Yang , Jian-Qiang Wang , Xianlong Du , Jian Lin . Rational design and synthesis of a uranyl-organic hybrid for X-ray scintillation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100275-100275. doi: 10.1016/j.cjsc.2024.100275

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(466)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142