Citation: Xin Dong, Jing Liang, Zhijin Xu, Huajie Wu, Lei Wang, Shihai You, Junhua Luo, Lina Li. Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection[J]. Chinese Chemical Letters, ;2024, 35(6): 108708. doi: 10.1016/j.cclet.2023.108708 shu

Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection

Xin Dong ^{a, b} ,
Jing Liang ^{a, b} ,
Zhijin Xu ^b ,
Huajie Wu ^b ,
Lei Wang ^b ,
Shihai You ^{b, c} ,
Junhua Luo ^{b, c, *,} ,
Lina Li ^{b, c, *,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350116, China
b.
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

jhluo@fjirsm.ac.cn

lilina@fjirsm.ac.cn

Received Date: 18 May 2023
Revised Date: 15 June 2023
Accepted Date: 19 June 2023
Available Online: 24 June 2023

Figures(4)

Lead-halide perovskites exhibit outstanding performance in X-ray detection due to their intrinsic features such as high charge carrier mobility, large atomic number, and long carrier lifetime, but the toxicity of lead is regarded as the major factor hindering their development. Here, we introduce organic molecule (R)-(-)-2-methylpiperazine (R-MPz) into the bismuth-based structure to synthesize lead-free (R)-(H₂MPz)BiI₅ (R-MBI). The high-quality centimeter-sized single crystals have been obtained, which show a low dark current and superior environmental stability. Particularly, the single-crystal device of R-MBI exhibits a high μτ product up to 1.88 × 10⁻⁴ cm²/V and a low trap density of 1.21 × 10¹⁰ cm⁻³. Further, the detector displays excellent detection sensitivity of 263.58 µC Gy_air⁻¹ cm⁻² and a favorable low detection limit of 4.35 µGy_air/s, both of which meet the requirement for medical diagnostics. These findings shed light on the exploration of innovative bismuth-based hybrid perovskites for high-performance X-ray detection.
- Perovskite,
- Lead-free,
- Bismuth-based,
- X-ray detection,
- Sensitivity
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