Citation: Yujing Li, Xiaojun Zhang, Zicheng Wang, Lina Zhao, Yuxin Li. Highly sensitive Fe³⁺ luminescence detection via single-ion adsorption[J]. Chinese Chemical Letters, ;2024, 35(1): 108532. doi: 10.1016/j.cclet.2023.108532 shu

Highly sensitive Fe³⁺ luminescence detection via single-ion adsorption

Yujing Li ^a ,
Xiaojun Zhang ^a ,
Zicheng Wang ^a ,
Lina Zhao ^{a, b} ,
Yuxin Li ^{a, *,}

a.
Key Laboratory of Function Inorganic Material Chemistry (MOE), School of Chemistry and Material Science, and School of Civil Engineering, Heilongjiang University, Harbin 150080, China
b.
Department of Food & Environmental Engineering, East University of Heilongjiang, Harbin 150066, China

liyuxin@hlju.edu.cn

Received Date: 27 March 2023
Revised Date: 13 April 2023
Accepted Date: 29 April 2023
Available Online: 2 May 2023

Figures(3)

To achieve a lower detection limit has always been a goal of analytical chemists. Herein, we demonstrate the first picomolar level detection capability for Fe³⁺ ion via luminescence detection technology. The results of structural analysis and theoretical calculation show that Fe³⁺ ions are adsorbed on the central node of Eu-DBM (DBM = dibenzoylmethane) sensor in the form of single ion at ultralow concentration. Subsequently, the pathways of photo-induced charge and energy transfer of the obtained Eu-DBM@Fe³⁺ material have been changed, from the initial DBM-to-Eu³⁺ before Fe³⁺ adsorption to the ultimate DBM-to-Fe³⁺ after adsorption process, which quenches the luminescence of Eu³⁺ ion. This work not only obtains the highly sensitive luminescence detection ability, but also innovatively proposes the single-ion adsorption mechanism, both of which have important scientific and application values for the development of more efficient detection agents in the future.
- Luminescence detection,
- Lanthanide complex,
- High sensitivity,
- Fe³⁺ ion,
- Single-ion adsorption
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Highly sensitive Fe³⁺ luminescence detection via single-ion adsorption