Citation: Gongxun Yu, Fenghui Yang, Xu Han, Qiongyao Song, Jiangtao Zheng, Ying Qi, Tianming Chen, Qian Shen, Jingxia Qiu, Sheng Li. Oxygen functional groups modified amorphous hollow carbon bowls for pseudocapacitive Zn-ion storage[J]. Chinese Chemical Letters, ;2023, 34(12): 108288. doi: 10.1016/j.cclet.2023.108288 shu

Oxygen functional groups modified amorphous hollow carbon bowls for pseudocapacitive Zn-ion storage

Gongxun Yu ^{a, c} ,
Fenghui Yang ^a ,
Xu Han ^a ,
Qiongyao Song ^c ,
Jiangtao Zheng ^c ,
Ying Qi ^a ,
Tianming Chen ^a ,
Qian Shen ^a ,
Jingxia Qiu ^{b, c, *,} ,
Sheng Li ^{a, *,}

a.
Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing 211816, China
b.
School of Physical and Mathematical Sciences, Nanjing Tech University (NanjingTech), Nanjing 211816, China
c.
Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China

jxqiu@njtech.edu.cn

iamsli@njtech.edu.cn

Received Date: 24 January 2023
Revised Date: 16 February 2023
Accepted Date: 1 March 2023
Available Online: 5 March 2023

Figures(4)

Carbon is a promising capacitive electrode material for Zn-ion hybrid supercapacitors (ZHSCs), as it is low-cost, environmentally friendly, controllable and adjustable. By now, achieving both high energy and high power with carbon electrodes is still challenging, limited by their intrinsic properties. In this work, we have designed and presented an amorphous hollow carbon bowl material with surface chemical modifications of oxygen groups to figure out these concerns. The preparation of bowl-like structures and the storage behavior between Zn²⁺ and oxygen functional groups have also been discussed. With the contributions from its unique hollow structure and surface functional groups, it can significantly enhance the electrode pseudocapacitance and the entire electrochemical performance.
- Zn-ion hybrid supercapacitors,
- Hollow carbon bowls,
- Oxygen groups,
- Pseudocapacitance,
- Zn-ion storage
1. [1]
  X. Zhang, Z. Pei, C. Wang, et al., Small 15 (2019) e1903817. doi: 10.1002/smll.201903817
2. [2]
  M. Shao, C. Sun, T. Chen, et al., J. Energy Chem. 65 (2022) 127–132. doi: 10.1016/j.jechem.2021.05.037
3. [3]
  S. Li, C. Huang, L. Gao, et al., Angew. Chem. Int. Ed. 50 (2022) e202211478.
4. [4]
  Y. Tan, S. Li, X. Zhao, et al., Adv. Energy Mater. 12 (2022) 2104001. doi: 10.1002/aenm.202104001
5. [5]
  X. Li, X. Liu, Y. Xiang, et al., Chin. Chem. Lett. 33 (2022) 3197–3202. doi: 10.1016/j.cclet.2021.10.014
6. [6]
  V. Vijayakumar, M. Ghosh, M. Kurian, et al., Small 16 (2020) e2002528. doi: 10.1002/smll.202002528
7. [7]
  S. Wang, Q. Wang, W. Zeng, et al., Nano-Micro Lett. 11 (2019) 70. doi: 10.1007/s40820-019-0301-1
8. [8]
  Z. Li, D. Chen, Y. An, et al., Energy Storage Mater. 28 (2020) 307–314. doi: 10.1016/j.ensm.2020.01.028
9. [9]
  Y. Shao, Z. Sun, Z. Tian, et al., Adv. Funct. Mater. 31 (2020) 2007843.
10. [10]
  Q. Wang, S. Wang, X. Guo, et al., Adv. Electron. Mater. 5 (2019) 1900537. doi: 10.1002/aelm.201900537
11. [11]
  P.A. Maughan, N. Tapia-Ruiz, N. Bimbo, Electrochim. Acta 341 (2020) 136061. doi: 10.1016/j.electacta.2020.136061
12. [12]
  H. He, J. Lian, C. Chen, Q. Xiong, M. Zhang, Chem. Eng. J. 421 (2021) 129786. doi: 10.1016/j.cej.2021.129786
13. [13]
  Z. Song, G. Zhang, X. Deng, et al., Adv. Funct. Mater. 32 (2022) 2205453. doi: 10.1002/adfm.202205453
14. [14]
  L. Miao, Y. Lv, D. Zhu, et al., Chin. Chem. Lett. 34 (2023) 107784. doi: 10.1016/j.cclet.2022.107784
15. [15]
  G. Sun, H. Yang, G. Zhang, et al., Energy Environ. Sci. 11 (2018) 3367–3374. doi: 10.1039/C8EE02567C
16. [16]
  G.H. An, J. Hong, S. Pak, et al., Adv. Energy Mater. 10 (2019) 1902981.
17. [17]
  Z. Song, G. Zhang, X. Deng, et al., Nano-Micro Lett. 14 (2022) 53. doi: 10.1007/s40820-022-00792-x
18. [18]
  L. Dong, X. Ma, Y. Li, et al., Energy Storage Mater. 13 (2018) 96–102. doi: 10.1016/j.ensm.2018.01.003
19. [19]
  Z. Liu, G. Li, T. Cui, et al., J. Solid State Electrochem. 22 (2017) 91–101.
20. [20]
  Z. Huang, T. Wang, H. Song, et al., Angew. Chem. Int. Ed. 60 (2021) 1011–1021. doi: 10.1002/anie.202012202
21. [21]
  F. Wan, L. Zhang, X. Wang, et al., Adv. Funct. Mater. 28 (2018) 1804975. doi: 10.1002/adfm.201804975
22. [22]
  L. Han, H. Huang, X. Fu, et al., Chem. Eng. J. 392 (2020) 123733. doi: 10.1016/j.cej.2019.123733
23. [23]
  H. Zhou, C. Liu, J.C. Wu, et al., J. Mater. Chem. A 7 (2019) 9708–9715. doi: 10.1039/C9TA01256G
24. [24]
  H. Liang, R. Shi, Y. Zhou, et al., ACS Energy Lett. 7 (2022) 4381–4388. doi: 10.1021/acsenergylett.2c02203
25. [25]
  S. Chen, G. Yang, X. Zhao, et al., Front. Chem. 8 (2020) 663. doi: 10.3389/fchem.2020.00663
26. [26]
  H. Zhang, O. Noonan, X. Huang, et al., ACS Nano 10 (2016) 4579–4586. doi: 10.1021/acsnano.6b00723
27. [27]
  J. Liu, S.Z. Qiao, H. Liu, et al., Angew. Chem. Int. Ed. 50 (2011) 5947–5951. doi: 10.1002/anie.201102011
28. [28]
  W. Ye, L. Wang, Y. Yin, et al., ACS Energy Lett. 6 (2021) 2145–2152. doi: 10.1021/acsenergylett.1c00456
29. [29]
  R. Fei, H. Wang, Q. Wang, et al., Adv. Energy Mater. 10 (2020) 2002741. doi: 10.1002/aenm.202002741
30. [30]
  F. Pei, T. An, J. Zang, et al., Adv. Energy Mater. 6 (2016) 1502539. doi: 10.1002/aenm.201502539
31. [31]
  X. Feng, H.H. Wu, B. Gao, et al., Nano Res. 15 (2021) 352–360.
32. [32]
  X. Deng, K. Zou, R. Momen, et al., Sci. Bull. 66 (2021) 1858–1868. doi: 10.1016/j.scib.2021.04.042
33. [33]
  Z. Miao, Y. Huang, J. Xin, et al., ACS Appl. Mater. Interfaces 11 (2019) 18044–18050. doi: 10.1021/acsami.9b04426
34. [34]
  Y. Peng, Z. Chen, R. Zhang, et al., Nano-Micro Lett. 13 (2021) 192. doi: 10.1007/s40820-021-00722-3
35. [35]
  J. Zhang, W. Lv, D. Zheng, et al., Adv. Energy Mater. 8 (2018) 1702395. doi: 10.1002/aenm.201702395
36. [36]
  X. Gao, H. Deng, Y. Fang, et al., Chin. Chem. Lett. 34 (2023) 107919. doi: 10.1016/j.cclet.2022.107919
37. [37]
  C. Huang, X. Zhao, Y. Xu, et al., ACS Sustain. Chem. Eng. 8 (2020) 16028–16036. doi: 10.1021/acssuschemeng.0c06525
38. [38]
  S. Zeng, X. Shi, D. Zheng, et al., Mater. Res. Bull. 135 (2021) 111134. doi: 10.1016/j.materresbull.2020.111134
39. [39]
  M. Krishnamoorthy, N. Jha, ACS Sustain. Chem. Eng. 7 (2019) 8475–8489. doi: 10.1021/acssuschemeng.9b00233
40. [40]
  Y. Tian, R. Amal, D.W. Wang, Front. Energy Res. 4 (2016) 34.
41. [41]
  Z. Song, L. Miao, L. Li, et al., J. Mater. Chem. A 8 (2020) 3717–3725. doi: 10.1039/C9TA13520K
42. [42]
  Z. Liang, H. Xia, L. Zhang, et al., Results Phys. 16 (2020) 102912. doi: 10.1016/j.rinp.2019.102912
43. [43]
  P. Liu, W. Liu, Y. Huang, et al., Energy Storage Mater. 25 (2020) 858–865. doi: 10.1016/j.ensm.2019.09.004
44. [44]
  S. Wu, Y. Chen, T. Jiao, et al., Adv. Energy Mater. 9 (2019) 1902915. doi: 10.1002/aenm.201902915
45. [45]
  H. Zhang, Q. Liu, Y. Fang, et al., Adv. Mater. 31 (2019) e1904948. doi: 10.1002/adma.201904948
46. [46]
  J. Yin, W. Zhang, W. Wang, et al., Adv. Energy Mater. 10 (2020) 2001705. doi: 10.1002/aenm.202001705
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