Citation: Yaping Gong, Xiaoxian Chen, Bingqing Zhao, Jun Wang, Weixiong Zhang, Xiaoming Chen. Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)[J]. Chinese Chemical Letters, ;2023, 34(12): 108282. doi: 10.1016/j.cclet.2023.108282 shu

Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

zhangwx6@mail.sysu.edu.cn

Received Date: 10 November 2022
Revised Date: 19 February 2023
Accepted Date: 28 February 2023
Available Online: 6 March 2023

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Two-dimensional organic-inorganic hybrid ferroelastics with high-temperature reversible phase transitions are very rare and have become one of the research hotspots in the field of ferroelastic materials. Herein, we report three new layered organic-inorganic hybrid perovskites based on halogen-substituted phenethylaminium, (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F (1), Cl (2) and Br (3)). They undergo structural phase transitions at 376/371 K, 436/430 K, and 421/411 K, respectively, between the isomorphic high-temperature phases (space group I4/mmm, Z = 2) and different room-temperature phases with the reduced structural symmetries, i.e., P2₁/a (Z = 2) in 1, (Z = 4) in 2, and P2₁/a (Z = 4) in 3, respectively. These ferroelastic transitions arise from the order-disorder transition of organic cations together with the synchronous displacement of inorganic layers, accompanying with ferroelastic spontaneous strains of 0.16, 0.13 and 0.12 for 1−3, respectively. By enriching layered perovskite ferroelastics based on halogen-substituted cations, this work provides important clues for exploring new ferroic materials based on hybrid crystals.
- Layered perovskite,
- Phase transition,
- Halogen-substituted,
- Ferroelastic,
- Spontaneous strain
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Ferroelastic phase transitions in three new layered perovskites: (3-XC6H5CH2CH2NH3)2[CdCl4] (X = F, Cl, and Br)

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通讯作者: 陈斌, bchen63@163.com

Ferroelastic phase transitions in three new layered perovskites: (3-XC₆H₅CH₂CH₂NH₃)₂[CdCl₄] (X = F, Cl, and Br)