Citation: Jianlu Sun, Ruiqi Tian, Yuehua Man, Yating Fei, Xiaosi Zhou. Templated synthesis of imine-based covalent organic framework hollow nanospheres for stable potassium-ion batteries[J]. Chinese Chemical Letters, ;2023, 34(7): 108233. doi: 10.1016/j.cclet.2023.108233 shu

Templated synthesis of imine-based covalent organic framework hollow nanospheres for stable potassium-ion batteries

School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China

zhouxiaosi@njnu.edu.cn

Received Date: 28 December 2022
Revised Date: 16 January 2023
Accepted Date: 15 February 2023
Available Online: 19 February 2023

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Covalent organic frameworks (COFs), as highly tunable porous crystalline materials, have promising applications in potassium-ion batteries (PIBs) due to their abundant charge carrier transport channels and excellent structural stability. However, the excessive stacking of interlayer electron clouds makes it difficult to expose internal active sites. Strategies to design functional COFs with controllable morphology and copious active sites are promising but still challenging. Herein, by utilizing the condensation between 1,3,5-triformylbenzene (TFB) and p-phenylenediamine (PPD) and using amino-modified SiO₂ nanospheres as templates, we synthesize core-shell NH₂-SiO₂@TP-COF. Through NaOH etching of NH₂-SiO₂@TP-COF, we obtain imine-based TP-COF hollow nanospheres, which shows excellent potassium storage performance when applied to the anode for PIBs. Ex-situ analysis and density functional theory calculations reveal that CN groups and benzenes are active sites for K⁺ storage.
- Potassium ion batteries,
- Anode,
- Covalent organic framework,
- Templated synthesis,
- Hollow nanospheres
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