Citation: Shu Niu, Hongyan Xiao, Xiao-Di Yang, Huan Cong. Chloride anion-induced dimer capsule based on a polyfluorinated macrocycle meta-WreathArene[J]. Chinese Chemical Letters, ;2023, 34(7): 108042. doi: 10.1016/j.cclet.2022.108042 shu

Chloride anion-induced dimer capsule based on a polyfluorinated macrocycle meta-WreathArene

Shu Niu ^a ,
Hongyan Xiao ^b ,
Xiao-Di Yang ^c ,
Huan Cong ^{a, *,}

a.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry; School of Future Technology, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190, China
b.
Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
c.
Research Center of Chiral Drugs, Innovation Research Institute of Traditional Chinese Medicine, Shanghai University of Traditional Chinese Medicine, Shanghai 200438, China

cong@mail.ipc.ac.cn

Received Date: 6 October 2022
Revised Date: 1 December 2022
Accepted Date: 5 December 2022
Available Online: 10 December 2022

Figures(5)

[1_n]metacyclophanes are a class of important building blocks for supramolecular assembly of artificial capsules. Herein we present the preparation and properties of a novel polyfluorinated macrocycle meta-WreathArene, a C₂-symmetrical [1₄]metacyclophane. Adopting a cone conformation in acetone solution, the macrocycle can form dimer capsules through hydrogen bonds induced by chloride anions. Each dimer capsule consists of two meta-WreathArene and two chloride anions, and has been unambiguously characterized both in solution and in solid state.
- Macrocycle,
- Metacyclophane,
- Anion,
- Assembly,
- Capsule
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