Citation: Ke Jiang, Yuntian Gao, Peng Zhang, Shiwei Lin, Ling Zhang. A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C₂H₂/CO₂ separation[J]. Chinese Chemical Letters, ;2023, 34(8): 108039. doi: 10.1016/j.cclet.2022.108039 shu

A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C₂H₂/CO₂ separation

Ke Jiang ^{b, c} ,
Yuntian Gao ^a ,
Peng Zhang ^a ,
Shiwei Lin ^a ,
Ling Zhang ^{a, *,}

a.
State Key Laboratory of Marine Resource Utilization in South China Sea, School of Materials Science and Engineering, Hainan University, Haikou 570228, China
b.
Key Laboratory of Food Nutrition and Functional Food of Hainan Province, School of Food Science and Engineering, Hainan University, Haikou 570228, China
c.
State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China

ling.zhang@hainanu.edu.cn

Received Date: 16 August 2022
Revised Date: 18 September 2022
Accepted Date: 2 December 2022
Available Online: 5 December 2022

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Adsorptive separation of acetylene (C₂H₂) from carbon dioxide (CO₂) is of great significance in petrochemical industry, but still remains as a daunting challenge by reason of their very similar molecular sizes/shapes and physical properties. Herein, we reported a new perchlorate-based hybrid ultramicroporous material ZJU-194 that features the unique flexible-robust network decorated with rich bare oxygen atoms. By integrating the refined pore space as well as specific binding sites, the activated ZJU-194 (ZJU-194a) enables a selective two-step gate-opening adsorption toward C₂H₂, but blocks off the further uptake of CO₂. It thus exhibits a very high C₂H₂/CO₂ selectivity (22.4) at ambient conditions, which is superior to most reported MOF materials. Its complete separation for 50/50 C₂H₂/CO₂ mixtures is further evidenced by the dynamic breakthrough experiments.
- Porous materials,
- Gas separation,
- Pore chemistry,
- Flexibility,
- Host-guest interaction
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A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C2H2/CO2 separation

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通讯作者: 陈斌, bchen63@163.com

A new perchlorate-based hybrid ultramicroporous material with rich bare oxygen atoms for high C₂H₂/CO₂ separation