Citation: Xiao-Hong Yi, Ya Gao, Chong-Chen Wang, Yu-Hang Li, Hong-Yu Chu, Peng Wang. Photocatalytic Cr(Ⅵ) reduction over MIL-88A(Fe) on polyurethane sponge: From batch to continuous-flow operation[J]. Chinese Chemical Letters, ;2023, 34(7): 108029. doi: 10.1016/j.cclet.2022.108029 shu

Photocatalytic Cr(Ⅵ) reduction over MIL-88A(Fe) on polyurethane sponge: From batch to continuous-flow operation

Xiao-Hong Yi ^{a, b} ,
Ya Gao ^{a, b} ,
Chong-Chen Wang ^{a, b, *,} ,
Yu-Hang Li ^{a, b} ,
Hong-Yu Chu ^{a, b} ,
Peng Wang ^{a, b}

a.
Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, School of Environment and Energy Engineering, Beijing University of Civil Engineering and Architecture, Beijing 100044, China
b.
Beijing Energy Conservation & Sustainable Urban and Rural Development Provincial and Ministry Co-construction Collaboration Innovation Center, Beijing University of Civil Engineering and Architecture, Beijing 100044, China

wangchongchen@bucea.edu.cn

Received Date: 6 September 2022
Revised Date: 14 November 2022
Accepted Date: 28 November 2022
Available Online: 30 November 2022

Figures(4)

MIL-88A(Fe)@sponge (MS) was synthesized by a dip-coating method, which displayed efficient photocatalytic Cr(Ⅵ) reduction efficiency under both low power LED UV light and real solar light irradiation. It was observed that MS (0.2 g/L) could remove 100% Cr(Ⅵ) (10 mg/L) by adding 0.4 mmol/L tartaric acid (TA) without adjusting pH (pH 5.05) within 6.0 min and 3.0 min under UV light and real solar light irradiation, respectively. Besides, the photo-induced e⁻ and radicals (O₂^•− and CO₂^•−) were found to play the momentous roles in the MS/TA/UVL/Cr(Ⅵ) system by the scavenger experiments and electron spin resonance (ESR) tests. MS was also filled into a fixed-bed reactor to test the possibility of long-term Cr(Ⅵ) reduction operation in TA/UVL system. As expected, the results revealed that MS could still maintain 100% activity up to 60 h. These results demonstrated that MIL-88A(Fe) might be the potentially efficient catalyst for large-scale wastewater treatment in the near future.
- MIL-88A(Fe),
- Polyurethane sponge,
- Cr(Ⅵ) reduction,
- Tartaric acid,
- Continuous operation
1. [1]
  R.P. Schwarzenbach, T. Egli, T.B. Hofstetter, U. von Gunten, B. Wehrli, Annu. Rev. Environ. Resour. 35 (2010) 109–136. doi: 10.1146/annurev-environ-100809-125342
2. [2]
  M. Wang, H.S. Tsai, C. Zhang, C. Wang, S.H. Ho, Chin. Chem. Lett. 33 (2022) 2807–2816. doi: 10.1016/j.cclet.2021.11.060
3. [3]
  Y. Dai, J. Yao, Y. Song, S. Wang, Y. Yuan, Environ. Sci. : Nano 3 (2016) 857–868. doi: 10.1039/C6EN00148C
4. [4]
  S.P. Wu, X.Z. Dai, J.R. Kan, F.D. Shilong, M.Y. Zhu, Chin. Chem. Lett. 28 (2017) 625–632. doi: 10.1016/j.cclet.2016.11.015
5. [5]
  S. Prasad, K.K. Yadav, S. Kumar, et al., J. Environ. Manag. 285 (2021) 112174. doi: 10.1016/j.jenvman.2021.112174
6. [6]
  C.C. Wang, X. Ren, P. Wang, C. Chang, Chemosphere 303 (2022) 134949. doi: 10.1016/j.chemosphere.2022.134949
7. [7]
  X. Liu, G. Liu, S. You, Chemosphere 263 (2021) 127898. doi: 10.1016/j.chemosphere.2020.127898
8. [8]
  Y.H. Li, X.H. Yi, Y.X. Li, et al., Environ. Res. 201 (2021) 111596. doi: 10.1016/j.envres.2021.111596
9. [9]
  R. Flyunt, M.N. Schuchmann, C. von Sonntag, Chemistry 7 (2001) 796–799. doi: 10.1002/1521-3765(20010216)7:4<796::AID-CHEM796>3.0.CO;2-J
10. [10]
  C. Zhu, Y. Li, Y. Zhang, et al., Colloid. Surf. A 642 (2022) 128657. doi: 10.1016/j.colsurfa.2022.128657
11. [11]
  C.Y. Wang, L. Ma, C.C. Wang, et al., Environ. Funct. Mater. 1 (2022) 49–66.
12. [12]
  J.S. Wang, X.H. Yi, X. Xu, et al., Chem. Eng. J. 431 (2022) 133213. doi: 10.1016/j.cej.2021.133213
13. [13]
  X.D. Du, X.H. Yi, P. Wang, et al., Chem. Eng. J. 356 (2019) 393–399. doi: 10.1016/j.cej.2018.09.084
14. [14]
  Q. Zhao, X.H. Yi, C.C. Wang, P. Wang, W. Zheng, Chem. Eng. J. 429 (2022) 132497. doi: 10.1016/j.cej.2021.132497
15. [15]
  X. Liao, F. Wang, F. Wang, et al., Appl. Catal. B: Environ. 259 (2019) 118064. doi: 10.1016/j.apcatb.2019.118064
16. [16]
  X.H. Yi, S.Q. Ma, X.D. Du, et al., Chem. Eng. J. 375 (2019) 121944. doi: 10.1016/j.cej.2019.121944
17. [17]
  W. Yang, Z. Yang, L. Shao, et al., J. Environ. Sci. 107 (2021) 194–204. doi: 10.1016/j.jes.2021.02.006
18. [18]
  Y.X. Li, C.C. Wang, H. Fu, P. Wang, J. Environ. Chem. Eng. 9 (2021) 105451. doi: 10.1016/j.jece.2021.105451
19. [19]
  J. Guo, J. Deng, B. An, et al., Chemosphere 295 (2022) 133785. doi: 10.1016/j.chemosphere.2022.133785
20. [20]
  B. Jiang, Y. Gong, J. Gao, et al., J. Hazard. Mater. 365 (2019) 205–226. doi: 10.1016/j.jhazmat.2018.10.070
21. [21]
  Y. Zhang, Y. Dai, L. Yin, et al., Catal. Sci. Technol. 10 (2020) 3654–3663. doi: 10.1039/D0CY00556H
22. [22]
  W. Liao, Z. Ye, S. Yuan, et al., Environ. Sci. Technol. 53 (2019) 13767–13775. doi: 10.1021/acs.est.9b05208
1. [1]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
2. [2]
  Shiyu Pan , Bo Cao , Deling Yuan , Tifeng Jiao , Qingrui Zhang , Shoufeng Tang . Complexes of cupric ion and tartaric acid enhanced calcium peroxide Fenton-like reaction for metronidazole degradation. Chinese Chemical Letters, 2024, 35(7): 109185-. doi: 10.1016/j.cclet.2023.109185
3. [3]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(Ⅵ) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-0. doi: 10.3866/PKU.WHXB202309020
4. [4]
  Ning Liu , Man Tian , Ye Zhang , Jinming Yang , Zhihao Wang , Wangxi Dai , Guixiang Quan , Jianqiu Lei , Xiaodong Zhang , Liang Tang . Three-dimensional MIL-88A(Fe)-derived α-Fe₂O₃ and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin. Chinese Chemical Letters, 2025, 36(12): 111063-. doi: 10.1016/j.cclet.2025.111063
5. [5]
  Jingtao Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Corrigendum to “Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation” [Chinese Chemical Letters 35 (2024) 109639]. Chinese Chemical Letters, 2025, 36(7): 110867-. doi: 10.1016/j.cclet.2025.110867
6. [6]
  Keying Qu , Jie Li , Ziqiu Lai , Kai Chen . Unveiling the Mystery of Chirality from Tartaric Acid. University Chemistry, 2024, 39(9): 369-378. doi: 10.12461/PKU.DXHX202310091
7. [7]
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8. [8]
  Xiaokang Hou , Huanxin Ma , Mengmeng Zhao , Chunhua Feng , Shishu Zhu . Unveiling role of Cu(Ⅱ) in photochemical transformation and reactive oxygen species production of schwertmannite in the presence of tartaric acid. Chinese Chemical Letters, 2025, 36(7): 110332-. doi: 10.1016/j.cclet.2024.110332
9. [9]
  Xun Zhu , Chenchen Zhang , Yingying Li , Yin Lu , Na Huang , Dawei Wang . Degradation of perfluorooctanoic acid by inductively heated Fenton-like process over the Fe₃O₄/MIL-101 composite. Chinese Chemical Letters, 2024, 35(12): 109753-. doi: 10.1016/j.cclet.2024.109753
10. [10]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
11. [11]
  Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756
12. [12]
  Yuexiang Liu , Xiangqiao Yang , Tong Lin , Guantian Yang , Xiaoyong Xu , Bubing Zeng , Zhong Li , Weiping Zhu , Xuhong Qian . Efficient continuous synthesis of 2-[3-(trifluoromethyl)phenyl]malonic acid, a key intermediate of Triflumezopyrim, coupling with esterification-condensation-hydrolysis. Chinese Chemical Letters, 2025, 36(1): 109747-. doi: 10.1016/j.cclet.2024.109747
13. [13]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
14. [14]
  Di Wang , Qing-Song Chen , Yi-Ran Lin , Yun-Xin Hou , Wei Han , Juan Yang , Xin Li , Zhen-Hai Wen . Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(8): 100346-100346. doi: 10.1016/j.cjsc.2024.100346
15. [15]
  Xin Zhou , Xuejia Li , Yujia Xiang , Heng Zhang , Chuanshu He , Zhaokun Xiong , Wei Li , Peng Zhou , Hongyu Zhou , Yang Liu , Bo Lai . The application of low-valent sulfur oxy-acid salts in advanced oxidation and reduction processes: A review. Chinese Chemical Letters, 2025, 36(9): 110664-. doi: 10.1016/j.cclet.2024.110664
16. [16]
  Hang Wang , Qi Wang , Chuan-De Wu . Continuous synthesis of ammonia. Chinese Journal of Structural Chemistry, 2025, 44(3): 100437-100437. doi: 10.1016/j.cjsc.2024.100437
17. [17]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
18. [18]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
19. [19]
  Yixin Sun , Keke Yu , Xiuchun Guo , Lanlan Zong , Zhonggui He , Xiaohui Pu . Three-in-one reduction and acid-ignited micelles amplify antitumor efficacy via precise synergistic delivery of paclitaxel and naringenin. Chinese Chemical Letters, 2025, 36(6): 110393-. doi: 10.1016/j.cclet.2024.110393
20. [20]
  Chao Liu , Liming Gong , Yanhong Liu , Shuangqing Wang , Hao Wu , Liqing Chen , Mingji Jin , Zhonggao Gao , Wei Huang . Lipoic acid-locked reduction-responsive core-cross-linked micelles delivering paclitaxel for triple-negative breast cancer treatment. Chinese Chemical Letters, 2025, 36(8): 110570-. doi: 10.1016/j.cclet.2024.110570

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